Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Identify te following compounds based on the spectra given.
![The image consists of four graphs, each representing different types of spectroscopic data commonly used in chemical analysis.
1. **Top Left Graph: Proton NMR Spectrum**
- The graph displays a proton nuclear magnetic resonance (NMR) spectrum.
- The x-axis is labeled "ppm" (parts per million), indicating chemical shift, which ranges from 0 to 10 ppm.
- Peaks are present near 1, 2, 4, 5, and 7-8 ppm.
- Integrations (noted as integral lines) above the peaks suggest the relative number of protons corresponding to each signal.
2. **Top Right Graph: Carbon-13 NMR Spectrum**
- This graph shows a carbon-13 NMR spectrum.
- The x-axis is labeled "ppm" and spans from 0 to 220 ppm.
- Peaks appear around 20, 50, 80, 120, and 180 ppm.
- These peaks correspond to the different carbon environments in the molecule.
3. **Middle Graph: Infrared (IR) Spectrum**
- The IR spectrum is displayed with the x-axis labeled as "WAVENUMBER cm⁻¹," ranging from 4500 to 500 cm⁻¹.
- The y-axis represents transmittance, decreasing from 100 to 0 percent.
- Numerous peaks suggest various functional groups and bonds, with significant absorbance around 1600, 1400, and 1000 cm⁻¹, indicating possible carbonyl, aromatic, and C-H bonding regions.
4. **Bottom Graph: Mass Spectrum**
- The graph presents a mass spectrum.
- The x-axis shows the mass-to-charge ratio (m/z), ranging from 0 to 150.
- The y-axis represents "relative intensity," ranging from 0 to 100%.
- Significant peaks at m/z values of approximately 29, 55, 73, and 100 suggest fragment ions of the analyzed compound.
These graphs provide a comprehensive insight into the molecular structure through various analytical techniques.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa1871893-1489-414f-ba40-94b584c7772f%2F24c76ba5-a72d-4b6c-8bff-213559844a1d%2Frmvbxpa_processed.png&w=3840&q=75)
Transcribed Image Text:The image consists of four graphs, each representing different types of spectroscopic data commonly used in chemical analysis.
1. **Top Left Graph: Proton NMR Spectrum**
- The graph displays a proton nuclear magnetic resonance (NMR) spectrum.
- The x-axis is labeled "ppm" (parts per million), indicating chemical shift, which ranges from 0 to 10 ppm.
- Peaks are present near 1, 2, 4, 5, and 7-8 ppm.
- Integrations (noted as integral lines) above the peaks suggest the relative number of protons corresponding to each signal.
2. **Top Right Graph: Carbon-13 NMR Spectrum**
- This graph shows a carbon-13 NMR spectrum.
- The x-axis is labeled "ppm" and spans from 0 to 220 ppm.
- Peaks appear around 20, 50, 80, 120, and 180 ppm.
- These peaks correspond to the different carbon environments in the molecule.
3. **Middle Graph: Infrared (IR) Spectrum**
- The IR spectrum is displayed with the x-axis labeled as "WAVENUMBER cm⁻¹," ranging from 4500 to 500 cm⁻¹.
- The y-axis represents transmittance, decreasing from 100 to 0 percent.
- Numerous peaks suggest various functional groups and bonds, with significant absorbance around 1600, 1400, and 1000 cm⁻¹, indicating possible carbonyl, aromatic, and C-H bonding regions.
4. **Bottom Graph: Mass Spectrum**
- The graph presents a mass spectrum.
- The x-axis shows the mass-to-charge ratio (m/z), ranging from 0 to 150.
- The y-axis represents "relative intensity," ranging from 0 to 100%.
- Significant peaks at m/z values of approximately 29, 55, 73, and 100 suggest fragment ions of the analyzed compound.
These graphs provide a comprehensive insight into the molecular structure through various analytical techniques.
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