i. The graph indicates the pH change during the titration of 20.0 cm³ of 0.100 mol dm-* of CH»COOH (aq)with 0.100 mol dmª KOH (aq). From the graph, identify the volume of KOH (aq) and the pH at the equivalence point. 14 13 Volume:, 12 11- pH: 10

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**Titration and pH Analysis**

**8.)**
**a.**

**i.** The graph indicates the pH change during the titration of 20.0 cm³ of 0.100 mol dm⁻³ of CH₃COOH (aq) with 0.100 mol dm⁻³ KOH (aq). From the graph, identify the volume of KOH (aq) and the pH at the equivalence point.

- **Volume:** ________________
- **pH:** ________________

**Explanation of the Graph:**

The provided graph shows a typical titration curve with the x-axis labeled "Volume of KOH (aq) added / cm³" ranging from 0 to 50 cm³, and the y-axis labeled "pH" ranging from 1 to 14. The curve starts at a low pH value indicating the acidic nature of CH₃COOH. As KOH is added, the pH gradually increases until it sharply rises at the equivalence point, where the amount of KOH added neutralizes the acetic acid present. Beyond this point, adding more KOH results in a higher pH typical of a basic solution.

**ii.** Sketch on the graph above, to indicate the change in pH during a titration of 25.0 cm³ of 0.100 mol dm⁻³ HNO₃ (aq) (Strong acid) with 0.100 mol dm⁻³ 0.100 KOH (aq) (strong base). On your graph, clearly indicate the starting pH value, the equivalence point, the pH at the equivalence point, and the final pH reached. (Describe the curve if you cannot sketch it).

**Description of the Curve:**

- **Starting pH Value:** Since HNO₃ is a strong acid, it will have an initial pH value close to 1.
- **Equivalence Point:** The equivalence point in the titration of a strong acid with a strong base will occur at a pH of 7.
- **Final pH:** Beyond the equivalence point, the addition of excess KOH will raise the pH significantly, approaching the strong base region around 13-14.

Initially, as a strong acid like HNO₃ is titrated with KOH, the pH starts at a low value. The pH will rise
Transcribed Image Text:**Titration and pH Analysis** **8.)** **a.** **i.** The graph indicates the pH change during the titration of 20.0 cm³ of 0.100 mol dm⁻³ of CH₃COOH (aq) with 0.100 mol dm⁻³ KOH (aq). From the graph, identify the volume of KOH (aq) and the pH at the equivalence point. - **Volume:** ________________ - **pH:** ________________ **Explanation of the Graph:** The provided graph shows a typical titration curve with the x-axis labeled "Volume of KOH (aq) added / cm³" ranging from 0 to 50 cm³, and the y-axis labeled "pH" ranging from 1 to 14. The curve starts at a low pH value indicating the acidic nature of CH₃COOH. As KOH is added, the pH gradually increases until it sharply rises at the equivalence point, where the amount of KOH added neutralizes the acetic acid present. Beyond this point, adding more KOH results in a higher pH typical of a basic solution. **ii.** Sketch on the graph above, to indicate the change in pH during a titration of 25.0 cm³ of 0.100 mol dm⁻³ HNO₃ (aq) (Strong acid) with 0.100 mol dm⁻³ 0.100 KOH (aq) (strong base). On your graph, clearly indicate the starting pH value, the equivalence point, the pH at the equivalence point, and the final pH reached. (Describe the curve if you cannot sketch it). **Description of the Curve:** - **Starting pH Value:** Since HNO₃ is a strong acid, it will have an initial pH value close to 1. - **Equivalence Point:** The equivalence point in the titration of a strong acid with a strong base will occur at a pH of 7. - **Final pH:** Beyond the equivalence point, the addition of excess KOH will raise the pH significantly, approaching the strong base region around 13-14. Initially, as a strong acid like HNO₃ is titrated with KOH, the pH starts at a low value. The pH will rise
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