I. Synthesize the corresponding alkyne from the given alkene. Show the steps (no need for the mechanism like transfer of electrons- just the arrowed steps) and the reagents needed in the steps CH3 -CH-CH=CH, CH3 II. Subject the resulting alkyne above to the following reactions (show also the steps and the reagents needed in the steps): a. hydration with mercury as catalyst b. oxidation with potassium permanganate c. hydrohalogenation with HCI (only one HCI is given) d. hydration with borane e. halogenation with bromine (2 molecules of bromine are given) f. hydrogenation with Lindlar catalyst g. hydrogenation with Li/NH3 h. hydrogenation with Pt/C III. If the above alkyne product in I. is subjected to acetylide formation followed by nucleophilic substitution by a primary alkyl halide, show how the following product is formed. CH3 CH3 CH3 -CH-C C-CH2 CH3- -CH-CH

I. Synthesize the corresponding alkyne from the given alkene. Show the steps (no need for the mechanism like transfer of electrons- just the arrowed steps) and the reagents needed in the steps CH3 -CH-CH=CH, CH3 II. Subject the resulting alkyne above to the following reactions (show also the steps and the reagents needed in the steps): a. hydration with mercury as catalyst b. oxidation with potassium permanganate c. hydrohalogenation with HCI (only one HCI is given) d. hydration with borane e. halogenation with bromine (2 molecules of bromine are given) f. hydrogenation with Lindlar catalyst g. hydrogenation with Li/NH3 h. hydrogenation with Pt/C III. If the above alkyne product in I. is subjected to acetylide formation followed by nucleophilic substitution by a primary alkyl halide, show how the following product is formed. CH3 CH3 CH3 -CH-C C-CH2 CH3- -CH-CH

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Reactions of Ethers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.

Question

100%

II. Handwritten

I. Synthesize the corresponding alkyne from the given alkene. Show the steps (no need for the
mechanism like transfer of electrons- just the arrowed steps) and the reagents needed in the
steps
CH3
-CH-CH=CH,
CH3
II. Subject the resulting alkyne above to the following reactions (show also the steps and the
reagents needed in the steps):
a. hydration with mercury as catalyst
b. oxidation with potassium permanganate
c. hydrohalogenation with HCI (only one HCl is given)
d. hydration with borane
e. halogenation with bromine (2 molecules of bromine are given)
f. hydrogenation with Lindlar catalyst
g. hydrogenation with Li/NH3
h. hydrogenation with Pt/C
III. If the above alkyne product in I. is subjected to acetylide formation followed by nucleophilic
substitution by a primary alkyl halide, show how the following product is formed.
CH3
CH3
CH3
-CH-C C-CH2
CH3-
-CH-CH

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