I. AHxn for the reaction below was determined using bond dissociation energies (BDES) to be -57 kJ. Using the table of BDE below, find the bond energy for H-Br. H C=C H H Br Н-С-ҫ-н + HBr H Bond С-С C=C C-H C-Br BDE (kJ/mol) 348 614 413 276 II. Use heats of formation to find the standard heat of reaction (AH°xn) for the reaction shown above. C2H4 and HBr are both gases and AH°; for CH3CH,Br (8) is -85.3 kJ/mol. Use T16-4-1 to find any additional values of AH°; needed.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

Could you please answer number 2 and 3

I. AHn for the reaction below was determined using bond dissociation energies (BDES) to be -57 kJ. Using the table of BDE below,
find the bond energy for H-Br.
'rxn
H Br
H
c=C
H
+ HBr
+ H-C-C-
H
Bond
С-С
C=C
C-H
С-Br
BDE (kJ/mol)
348
614
413
276
II. Use heats of formation to find the standard heat of reaction (AH° rxn) for the reaction shown above. C2H4 and HBr are both gases and
AH°; for CH3CH2B (8) is -85.3 kJ/mol. Use T16-4-1 to find any additional values of AH°; needed.
III. Why is there a dfference between the reaction enthalpies calculated by these different approaches?
Transcribed Image Text:I. AHn for the reaction below was determined using bond dissociation energies (BDES) to be -57 kJ. Using the table of BDE below, find the bond energy for H-Br. 'rxn H Br H c=C H + HBr + H-C-C- H Bond С-С C=C C-H С-Br BDE (kJ/mol) 348 614 413 276 II. Use heats of formation to find the standard heat of reaction (AH° rxn) for the reaction shown above. C2H4 and HBr are both gases and AH°; for CH3CH2B (8) is -85.3 kJ/mol. Use T16-4-1 to find any additional values of AH°; needed. III. Why is there a dfference between the reaction enthalpies calculated by these different approaches?
The standard enthalpies of formation are available for a large number of compounds
in thermodynamic tables
Table T16-4-1. Selected standard enthalpies of formation, AH°;(298 K, 1 atm)
AH°f
AH°f
Substance
Formula
Substance
Formula
(kJ/mol)
(kJ/mol)
acetic acid
C2H4O2(!)
-487.0 hydrogen bromide
HBr(g)
-36.2
- .......
acetylene
C2H2(g)
226.8 hydrogen chloride
HCI(g)
-92.3
ammonia
NH 3(g)
-46.2 hydrogen fluoride
HF(g)
-268.6
aluminum oxide
Al 203(s)
-1675.7 hydrogen iodide
HI(g)
25.9
-.................
benzene
C6H6(t)
49.0 hydrogen peroxide
H202({)
-187.8
bromine
Br 2(g)
30.907 iron(II) oxide
Fe203(s)
-824.2
calcium carbonate
CaCO 3(s)
-1207.1 methane
CH 4(g)
-74.8
calcium oxide
CaO(s)
-635.5 methanol
CH3OH(t)
-238.6
carbon dioxide
CO 2(g)
-393.5
O 3(g)
142.3
Ozone
carbon monoxide
CO(g)
-110.5 propane
C3H8(g)
-103.8
carbon tetrachloride
CCI 4(!)
-193.3 silver chloride
AgCI( s)
-127.0
diamond
C(s)
1.9 sodium bicarbonate
NaHCO 3(s)
-947.7
ethane
C2H6(g)
-84.7 sodium carbonate
Na 2CO3(s)
-1130.9
ethanol
C2H5OH(g)
-235.1 sodium chloride
NaCI(s)
-410.9
ethanol
C2H5OH(?)
-277.7 sodium hydroxide
NaOH(s)
-425.6
ethyl bromide
C2H3Br(g)
-97.6
sucrose
C 12H22011(s)
-2221.0
ethylene
C2H4(g)
52.3 sulfur trioxide
SO 3(g)
-395.2
formaldehyde
CH20(g)
-108.6 water
H20(t)
-285.8
glucose
C6H1206(s)
-1273.0 water vapor
H20(g)
-241.8
Transcribed Image Text:The standard enthalpies of formation are available for a large number of compounds in thermodynamic tables Table T16-4-1. Selected standard enthalpies of formation, AH°;(298 K, 1 atm) AH°f AH°f Substance Formula Substance Formula (kJ/mol) (kJ/mol) acetic acid C2H4O2(!) -487.0 hydrogen bromide HBr(g) -36.2 - ....... acetylene C2H2(g) 226.8 hydrogen chloride HCI(g) -92.3 ammonia NH 3(g) -46.2 hydrogen fluoride HF(g) -268.6 aluminum oxide Al 203(s) -1675.7 hydrogen iodide HI(g) 25.9 -................. benzene C6H6(t) 49.0 hydrogen peroxide H202({) -187.8 bromine Br 2(g) 30.907 iron(II) oxide Fe203(s) -824.2 calcium carbonate CaCO 3(s) -1207.1 methane CH 4(g) -74.8 calcium oxide CaO(s) -635.5 methanol CH3OH(t) -238.6 carbon dioxide CO 2(g) -393.5 O 3(g) 142.3 Ozone carbon monoxide CO(g) -110.5 propane C3H8(g) -103.8 carbon tetrachloride CCI 4(!) -193.3 silver chloride AgCI( s) -127.0 diamond C(s) 1.9 sodium bicarbonate NaHCO 3(s) -947.7 ethane C2H6(g) -84.7 sodium carbonate Na 2CO3(s) -1130.9 ethanol C2H5OH(g) -235.1 sodium chloride NaCI(s) -410.9 ethanol C2H5OH(?) -277.7 sodium hydroxide NaOH(s) -425.6 ethyl bromide C2H3Br(g) -97.6 sucrose C 12H22011(s) -2221.0 ethylene C2H4(g) 52.3 sulfur trioxide SO 3(g) -395.2 formaldehyde CH20(g) -108.6 water H20(t) -285.8 glucose C6H1206(s) -1273.0 water vapor H20(g) -241.8
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Types of Bonds
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY