(i) Ruby (contains Cr³+ in Al2O3), red. (ii) Sapphire (contains Fe²+ and Ti4* in Al2O3), intense blue. (iii) Cr₂O7², deep orange. (iv) [WO4], colourless but shows a very strong band in the UV. (v) [Fe(bpy)3]2+, deep red.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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what kind of electronic transitions are responsible for the colours of the following species? For each case, state the type of the electronic transition, the orbitals between which the transition occurs and briefly explain the reason for your assignment.

(i) Ruby (contains Cr³+ in Al2O3), red.
(ii) Sapphire (contains Fe²+ and Ti4* in Al2O3), intense blue.
(iii) Cr₂O7², deep orange.
(iv) [WO4], colourless but shows a very strong band in the UV.
(v) [Fe(bpy)3]2+, deep red.
Transcribed Image Text:(i) Ruby (contains Cr³+ in Al2O3), red. (ii) Sapphire (contains Fe²+ and Ti4* in Al2O3), intense blue. (iii) Cr₂O7², deep orange. (iv) [WO4], colourless but shows a very strong band in the UV. (v) [Fe(bpy)3]2+, deep red.
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