I Review | Learning Goal: To understand how elementary steps make up a mechanism and how the rate law for an elementary step can be determined. Very often, a reaction does not tell us the whole story. For instance, the reaction Submit NO2(9) + CO(g)→NO(g)+ CO2(9) does not involve a collision between an NO2 molecule and a CO molecule. Based on experimental data at moderate temperatures, this reaction is thought to occur in the following two steps: Part B 1. NO2(9) + NO2(9)→NO3(g)+N0(g) 2. NO3(9) + CO(9)→CO2(9) +NO2(9) Which species is a reaction intermediate? • View Available Hint(s) Each individual step is called an elementary step. Together, these elementary steps are called the reaction mechanism. Overall, the resulting reaction is NO2(9) + CO(9)→NO(9) + CO2(9) Notice that in the elementary steps NO3 appears both as a product and then as a reactant; therefore it cancels out of the final chemical equation. NO3 is called a reaction intermediate. Also notice that 2 molecules of NO2 appear in the reactants of the first step and 1 molecule of NO2 appears as product of the second step, the net effect leaves only 1 molecule of NO2 as a reactant in the net equation. Submit Molecularity is the proper term for "how the molecules collide" in a reaction. For example, step 1 is bimolecular because it involves the collision of two molecules. Step 2 is also bimolecular for the same reason. Unimolecular reactions involve only one molecule in the reactants. Though rare, collisions among three molecules can occur. Such a reaction would be called termolecular. Part C What is the rate law for step 1 of this reaction? Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3. • View Available Hint(s) Rate = Submit Part D What is the rate law for step 2 of this reaction? Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3. • View Available Hint(s) Rate = Submit Provide Feedback

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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please answer part c and d

I Review |
Learning Goal:
To understand how elementary steps make up a mechanism and how the rate law for an
elementary step can be determined.
Very often, a reaction does not tell us the whole story. For instance, the reaction
Submit
NO2(9) + CO(g)→NO(g)+ CO2(9)
does not involve a collision between an NO2 molecule and a CO molecule. Based on
experimental data at moderate temperatures, this reaction is thought to occur in the following two
steps:
Part B
1. NO2(9) + NO2(9)→NO3(g)+N0(g)
2. NO3(9) + CO(9)→CO2(9) +NO2(9)
Which species is a reaction intermediate?
• View Available Hint(s)
Each individual step is called an elementary step. Together, these elementary steps are called the
reaction mechanism.
Overall, the resulting reaction is
NO2(9) + CO(9)→NO(9) + CO2(9)
Notice that in the elementary steps NO3 appears both as a product and then as a reactant;
therefore it cancels out of the final chemical equation. NO3 is called a reaction intermediate. Also
notice that 2 molecules of NO2 appear in the reactants of the first step and 1 molecule of NO2
appears as product of the second step, the net effect leaves only 1 molecule of NO2 as a
reactant in the net equation.
Submit
Molecularity is the proper term for "how the molecules collide" in a reaction. For example, step 1 is
bimolecular because it involves the collision of two molecules. Step 2 is also bimolecular for the
same reason. Unimolecular reactions involve only one molecule in the reactants. Though rare,
collisions among three molecules can occur. Such a reaction would be called termolecular.
Part C
What is the rate law for step 1 of this reaction?
Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3.
• View Available Hint(s)
Rate =
Submit
Part D
What is the rate law for step 2 of this reaction?
Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3.
• View Available Hint(s)
Rate =
Submit
Provide Feedback
Transcribed Image Text:I Review | Learning Goal: To understand how elementary steps make up a mechanism and how the rate law for an elementary step can be determined. Very often, a reaction does not tell us the whole story. For instance, the reaction Submit NO2(9) + CO(g)→NO(g)+ CO2(9) does not involve a collision between an NO2 molecule and a CO molecule. Based on experimental data at moderate temperatures, this reaction is thought to occur in the following two steps: Part B 1. NO2(9) + NO2(9)→NO3(g)+N0(g) 2. NO3(9) + CO(9)→CO2(9) +NO2(9) Which species is a reaction intermediate? • View Available Hint(s) Each individual step is called an elementary step. Together, these elementary steps are called the reaction mechanism. Overall, the resulting reaction is NO2(9) + CO(9)→NO(9) + CO2(9) Notice that in the elementary steps NO3 appears both as a product and then as a reactant; therefore it cancels out of the final chemical equation. NO3 is called a reaction intermediate. Also notice that 2 molecules of NO2 appear in the reactants of the first step and 1 molecule of NO2 appears as product of the second step, the net effect leaves only 1 molecule of NO2 as a reactant in the net equation. Submit Molecularity is the proper term for "how the molecules collide" in a reaction. For example, step 1 is bimolecular because it involves the collision of two molecules. Step 2 is also bimolecular for the same reason. Unimolecular reactions involve only one molecule in the reactants. Though rare, collisions among three molecules can occur. Such a reaction would be called termolecular. Part C What is the rate law for step 1 of this reaction? Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3. • View Available Hint(s) Rate = Submit Part D What is the rate law for step 2 of this reaction? Express your answer in standard MasteringChemistry notation. For example, if the rate law is k[A][C]3 type k* [A] * [C]^3. • View Available Hint(s) Rate = Submit Provide Feedback
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