Answered: + I- + H,0 u OH2

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Consider the following S_N1 reaction.
a.Draw a mechanism for this reaction using curved arrows.

b.Draw an energy diagram. Label the axes, starting material, product, E_a, and ΔH°. Assume that the starting material and product are equal in energy.

c.Draw the structure of any transition states.

d.What is the rate equation for this reaction?

e. What happens to the reaction rate in each of the following instances? [1] The leaving group is changed from I⁻ to Cl⁻; [2] The solvent is changed from H₂O to DMF; [3] The alkyl halide is changed from (CH₃)₂C(I)CH₂CH₃ to (CH₃)₂CHCH(I)CH₃; and [4] The concentrations of both the alkyl halide and H₂O are increased by a factor of five.

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