I arther: Chair conformers Monosubstituted rings The A-value for methyl, ethyl, isopropyl, and t-butyl substitution on a cyclohexane ring are 7.1kJ/mol, 7.3 kJ/mol, 9.0kJ/mol, and 18.8 kJ/mol, respectively.. Me Me 1. Et 95:5 95:5 Bu Bu 97:3 9995:5 Build the molecules and use your model to explain why the increased size of the substituent doe- not have a dramatic effect until you reach t-butyl. In other words, is it possible for the first three substituents (methyl, ethyl, and isopropyl) to achieve conformation in which 1,3-diaxial interactions are minimized? has -value: 0 9kJ/mol. Build the molecule in order to deterr
I arther: Chair conformers Monosubstituted rings The A-value for methyl, ethyl, isopropyl, and t-butyl substitution on a cyclohexane ring are 7.1kJ/mol, 7.3 kJ/mol, 9.0kJ/mol, and 18.8 kJ/mol, respectively.. Me Me 1. Et 95:5 95:5 Bu Bu 97:3 9995:5 Build the molecules and use your model to explain why the increased size of the substituent doe- not have a dramatic effect until you reach t-butyl. In other words, is it possible for the first three substituents (methyl, ethyl, and isopropyl) to achieve conformation in which 1,3-diaxial interactions are minimized? has -value: 0 9kJ/mol. Build the molecule in order to deterr
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![I arther:
Chair conformers
Monosubstituted rings
The A-value for methyl, ethyl, isopropyl, and t-butyl substitution on a cyclohexane ring are
7.1kJ/mol, 7.3 kJ/mol, 9.0kJ/mol, and 18.8 kJ/mol, respectively..
Me
Me
1.
Et
95:5
95:5
Bu
Bu
97:3
9995:5
Build the molecules and use your model to explain why the increased size of the substituent doe-
not have a dramatic effect until you reach t-butyl. In other words, is it possible for the first three
substituents (methyl, ethyl, and isopropyl) to achieve conformation in which 1,3-diaxial
interactions are minimized?
mlugiest bn
todte
has
-value: 0 9k.J/mol. Build the molecule in order to deterr](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc3fa3643-7cf2-4701-82b6-d843af10729d%2F391dbfec-e591-4382-9650-09b3bb2c556f%2Ftd3cgx_processed.jpeg&w=3840&q=75)
Transcribed Image Text:I arther:
Chair conformers
Monosubstituted rings
The A-value for methyl, ethyl, isopropyl, and t-butyl substitution on a cyclohexane ring are
7.1kJ/mol, 7.3 kJ/mol, 9.0kJ/mol, and 18.8 kJ/mol, respectively..
Me
Me
1.
Et
95:5
95:5
Bu
Bu
97:3
9995:5
Build the molecules and use your model to explain why the increased size of the substituent doe-
not have a dramatic effect until you reach t-butyl. In other words, is it possible for the first three
substituents (methyl, ethyl, and isopropyl) to achieve conformation in which 1,3-diaxial
interactions are minimized?
mlugiest bn
todte
has
-value: 0 9k.J/mol. Build the molecule in order to deterr
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