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- A 0.4852g sample of an iron ore was dissolved in acid to the 3+ state, then precipitated as Fe2O3 x H2O. The pp was filtered, washed and calcined to Fe2O3, which gave a weight of 0.2481g. Calculate the Fe % in the sample.Gold can be determined in solutions containing high concentrations of diverse ions by ICP. Aliquots of 50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared containing 10.0 mg/L Au in 20% H2SO4, and quantities of this solutions were added to the sample solution to give 0, 2.5, 5 and 10 mg/L added Au in each of the flask. The solutions were made up to a total volume of 100.0 mL, mixed and analyzed by ICP. The resulting data are presented in the following table: Added Au (mg/L) Emission Intensity (Counts) 0.0 12568 2.5 19324 5.0 26622 10.0 40021 a) Attach an excel graph for the determination showing the X intercept. b) Calculate the concentration of gold in the sample, report with its uncertainty. c) The known concentration of gold in the sample is 8.51 mg/L. Test the hypothesis that your result is equal to this value at the 95% confidence level. l2. In a laboratory experiment you react 20.0 mL of 25% by mass C2H&N2 with 8.000 NiCl2.6H20 to obtain the product Ni(NH2CH2CH½NH2j3Cl2 complex. The C2H3N2 solution used in this experiment is 25.0% by mass, with a density (d) of 0.950 g/mL. (MW NICI2.6H2O= 237.69 g/mole, MW C2HgN2=60.10 g/mole, MW tris(ethylenediamine)nickel(II)chloride = 309.89 g/mole) a. Write down the balanced equation of the synthesis. b. Determine the number of moles of each reactant that you use. c. Determine which reactant is the limiting reactant, giving your reasoning. Show all your work to get full credit. (5 points) d. Calculate your percent yield if the dry product weighs 7.000 g.
- 2 MnO4- (aq) + 5 C2O42- (aq) + 16 H+ (aq) « 2Mn2+ (aq) + 10 CO2 (g) + 8 H2O(l) 0.4040 g of the unknown compound (K2Zy(C2O4)z . nH2O) was dissolved in 100.0 mL water to make a solution. It was then heated to 80oC and titrated with a KMnO4 solution as shown below: The molarity of KMnO4 = 0.0.02321 M Volume used = 29.25 mL A.) What is the % Oxalate by mass for the unknown solid titrated?The absorbances of solutions containing K2CrO4 in 0.05 M KOH were measured in a 1.0-cm cell of 375 nm. The following results were obtained: Calculate the concentration of K2CrO4 (g/L) if the A is 0.550.A standard iron solution was prepared by dissolving 0.0140 g of pure iron in acid then transferring to a 50.00 mL volumetric flask with orthophenanthroline as a complexing agent. At a wavelength of 540 nm, the absorbance of the standard was 0.214 in a 1.00 cm cuvette. A 0.128 g sample of an iron ore was crushed and digested in 5 mL of concentrated acid. The digested sample was then transferred to a 10.00 mL volumetric flask and diluted to the mark with water. A 1.00 mL aliquot of the sample was transferred to a 25.00 mL volumetric flask, and diluted to the mark with water. A portion of the diluted sample was then transferred to a 1.00 cm cuvette and measured at a wavelength of 540 nm. The resulting absorbance was 0.216. Determine the % w/w of Fe in the iron ore.
- 4To measure the iron content of runoff from a ranch a 25.0 mL sample of run off was acidified with HNO3 and treated with excess KSCN to form a red complex. (KSCN itself is colorless.) The solution was then diluted to 100 mL and put into a variable pathlenght cell. For comparison, a 10.0 mL reference sample of 6.80 x 10-4 M Fe3+ was treated with HNO3 and KSCN and diluted to 50.0 mL. The reference was placed in a cell with a 1.00 cm pathlenght. The runoff had the same absorbance as the reference when the pathlenght of the runoff cell was 2.48 cm. What wa the concentraton of iron in the runoff?Potentially Useful Information Spectrochemical Series: | < Br < SCN < Cl° < NO3¯< F° < OH° < C2O4²- ~ H2O < NCS < NH3 < en < PPH3 A student synthesizes and isolates the following coordination compound [Ni(H2NCH2CH2NH2)3]Cl2 (molar mass = 309.8966 g/mol) according to the balanced reaction below. In the experiment, the student reacts 2.500 g of nickel (II) chloride hexahydrate (molar mass = 237.6878 g/mol) with 4.000 g of ethylenediamine (molar mass = 60.0992 g/mol). After isolating the product, the student collects 3.200 g of the nickel coordination compound. NICI2•6H2O (aq) + 3H2NCH2CH2NH2 (1) → [Ni(H2NCH2CH2NH2)3]Cl2 (s) + 6H2O (1) What is the limiting reactant in the reaction above? In this reaction, the limiting reactant is... O ethylenediamine O nickel (II) chloride hexahydrate O This reaction is stoichiometric, so there is no limiting reactant.
- Gold can be determined in solutions containing high concentrations of diverse ions by ICP-AES. Aliquots of 50.0 mL of the sample solution were transferred to each of four 100.0 mL volumetric flasks. A solution was prepared containing 10.0 mg/L Au in 20% H2SO4 and quantities of this solution were added to the sample solutions to give 0, 2.5, 5, and 10 mg/L added Au in each of the flasks. The solutions were made up to a total volume of 100.0 mL, mixed, and analysed by ICP-AES. The resulting data are presented in the following table. Added Au, mg/L Emission Intensity Count 12,568 19,324 26,622 40,021 0.0 2.5 5.0 10.0 Calculate the concentration of gold in the original sample.A 0.5962 g sample of iron ore is dissolved in perchloric acid (HCIO4). All iron present is oxidized to Fe3*. The solution is filtered to remove solid matrix materials and made basic with addition of ammonium hydroxide. The iron precipitates as the Fe(OH)3.XH2O gel. The precipitate is collected in a cistern crucible and ignited to produce Fe203. What is the wt. % of iron in the sample if the analysis produced 0.3210 g Fe2O3? Fe3+ + 3 OH → Fe,O3 + → Fe203 H2 18.83% 9.415% 56.49% O 37.66%2. 100.0-mL sample of spring water was treated to convert any iron present to Fe2*. Addition of 25.00 mL of 0.002107 M K2Cr207 resulted in the reaction 6FE2+ + Cr20,2- + 14H* ® 6F€³+ + 2Cr3+ + 7H2O The excess K2C1207 was back-titrated with 7.47 mL of a 0.00979 M Fe2+ solution. Calculate iron concentration (molarity) in the sample.