Homework Help is Here – Start Your Trial Now!
Science
Chemistry
how would you properly balance this reaction?

how would you properly balance this reaction?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question
5 how would you properly balance this reaction?
to form a primary alcohol. The aldehyde is citral, a component of essential oils from a number of sources including lemon myrtle, lemongrass, lemon tea-tree (70-90% of the essential oil), and to a lesser extent lemon, lime, and orange (2-10% of the essential oil). Citral is a mixture of (E)-3,7-dimethyl-2,6-octadi- enal (geranial) and (Z)-3,7-dimethyl-2,6-octadienal (neral). Reduction with sodium borohydride produces a mixture of (E)-3,7-dimethyl-2,6-octadienol (geraniol) and (Z)-3,7-dimethyl-2,6-octadienol (nerol) (Scheme 6-5). Notice that the reaction depicted in Scheme 6-5 is not balanced, how would you prop- erly balance this reaction? All of these compounds are fragrances used in the perfume industry. Students should detect a noticeable difference in the odors of citral and the geraniol/nerol mixture. Guanidinium chloride is added as an electrophilic catalyst that activates the aldehyde to nucleophilic attack. The reaction is remarkably regioselective because only the C=O bond is reduced, leaving both C=C bonds untouched. geranial NABH4 geraniol HO NH, CI H2N NH2 THF/H20 neral nerol Scheme 6-5. NABH, reduction of citral to citrol.
Transcribed Image Text:to form a primary alcohol. The aldehyde is citral, a component of essential oils from a number of sources including lemon myrtle, lemongrass, lemon tea-tree (70-90% of the essential oil), and to a lesser extent lemon, lime, and orange (2-10% of the essential oil). Citral is a mixture of (E)-3,7-dimethyl-2,6-octadi- enal (geranial) and (Z)-3,7-dimethyl-2,6-octadienal (neral). Reduction with sodium borohydride produces a mixture of (E)-3,7-dimethyl-2,6-octadienol (geraniol) and (Z)-3,7-dimethyl-2,6-octadienol (nerol) (Scheme 6-5). Notice that the reaction depicted in Scheme 6-5 is not balanced, how would you prop- erly balance this reaction? All of these compounds are fragrances used in the perfume industry. Students should detect a noticeable difference in the odors of citral and the geraniol/nerol mixture. Guanidinium chloride is added as an electrophilic catalyst that activates the aldehyde to nucleophilic attack. The reaction is remarkably regioselective because only the C=O bond is reduced, leaving both C=C bonds untouched. geranial NABH4 geraniol HO NH, CI H2N NH2 THF/H20 neral nerol Scheme 6-5. NABH, reduction of citral to citrol.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 4 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS