Homework Help is Here – Start Your Trial Now!
Science
Chemistry
How to apply Raoult's law to real solutions Consider mixing a liquid with a vapor pressure of 100 torr with an equimolar amount of a liquid with a vapor pressure of 200 torr. The resulting solution would be predicted to have a vapor pressure of 150 torr if it behaved ideally. If, however, the interactions between the different components are not similar we can see positive or negative deviations from the calculated vapor pressure. An actual vapor pressure greater than that predicted by Raoult's law is said to be a positive deviation and an actual vapor pressure lower than that predicted by Raoult's law is a negative deviation. Part A Imagine a solution of two liquids in which the molecules interact less favorably than they do in the individual liquids. Will this solution deviate positively from, deviate negatively from, or ideally follow Raoult's law? • View Available Hint(s) It will deviate positively. O t will deviate negatively. O It will be an ideal solution.

How to apply Raoult's law to real solutions Consider mixing a liquid with a vapor pressure of 100 torr with an equimolar amount of a liquid with a vapor pressure of 200 torr. The resulting solution would be predicted to have a vapor pressure of 150 torr if it behaved ideally. If, however, the interactions between the different components are not similar we can see positive or negative deviations from the calculated vapor pressure. An actual vapor pressure greater than that predicted by Raoult's law is said to be a positive deviation and an actual vapor pressure lower than that predicted by Raoult's law is a negative deviation. Part A Imagine a solution of two liquids in which the molecules interact less favorably than they do in the individual liquids. Will this solution deviate positively from, deviate negatively from, or ideally follow Raoult's law? • View Available Hint(s) It will deviate positively. O t will deviate negatively. O It will be an ideal solution.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question
100%
Learning Goal: To understand deviations from the ideal vapor pressure for solutions of two liquids. How to apply Raoult's law to real solutions Raoult's law is used to predict the vapor pressure of an ideal solution that contains one or more volatile components. For a solution with only one component Consider mixing a liquid with a vapor pressure of 100 torr with an equimolar amount of a liquid with a vapor pressure of 200 torr. The resulting solution would be predicted to have a vapor pressure of 150 torr if it behaved ideally. If, however, the interactions between the different components are not similar we can see positive or negative deviations from the calculated vapor pressure. An actual vapor pressure greater than that predicted by Raoult's law is said to be a positive deviation and an actual vapor pressure lower than that predicted by Raoult's law is a negative deviation. Psoln = Prolv X Xolv where Psoln is the vapor pressure of gaseous solvent above the solution, Psoly is the vapor pressure of the pure solvent, and Xsolv is the mole fraction of the solvent. Part A Imagine a solution of two liquids in which the molecules interact less favorably than they do in the individual liquids. Will this solution deviate positively from, deviate negatively from, or ideally follow Raoult's law? An assumption of Raoult's law is that the interactions between the different components of the solution are similar in magnitude to the interactions of each of the components with themselves; in other words, the components form an ideal solution. Deviations from this law are observed when interactions between solute and solvent are not similar. • View Available Hint(s) O t will deviate positively. O It will deviate negatively. O It will be an ideal solution.
Transcribed Image Text:Learning Goal: To understand deviations from the ideal vapor pressure for solutions of two liquids. How to apply Raoult's law to real solutions Raoult's law is used to predict the vapor pressure of an ideal solution that contains one or more volatile components. For a solution with only one component Consider mixing a liquid with a vapor pressure of 100 torr with an equimolar amount of a liquid with a vapor pressure of 200 torr. The resulting solution would be predicted to have a vapor pressure of 150 torr if it behaved ideally. If, however, the interactions between the different components are not similar we can see positive or negative deviations from the calculated vapor pressure. An actual vapor pressure greater than that predicted by Raoult's law is said to be a positive deviation and an actual vapor pressure lower than that predicted by Raoult's law is a negative deviation. Psoln = Prolv X Xolv where Psoln is the vapor pressure of gaseous solvent above the solution, Psoly is the vapor pressure of the pure solvent, and Xsolv is the mole fraction of the solvent. Part A Imagine a solution of two liquids in which the molecules interact less favorably than they do in the individual liquids. Will this solution deviate positively from, deviate negatively from, or ideally follow Raoult's law? An assumption of Raoult's law is that the interactions between the different components of the solution are similar in magnitude to the interactions of each of the components with themselves; in other words, the components form an ideal solution. Deviations from this law are observed when interactions between solute and solvent are not similar. • View Available Hint(s) O t will deviate positively. O It will deviate negatively. O It will be an ideal solution.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 1 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Solutions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS