How many Seconds are reQuircd to deposst o.2859 Or Cadmium metal from a Solutior that Contams cazt ions if a Current or Oileos A is applied n And 225 g or Magnesium metal in 30.n Seconds fram a Solutiorn That (ontams Mg?t ions A तपार एरे एुने

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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### Electrochemistry Calculation Problems

**Problem 1:**

How many seconds are required to deposit 0.285 g of Cadmium metal from a solution that contains \( Cd^{2+} \) ions if a current of 0.105 A is applied?

\[ \boxed{\text{___} \text{S}} \]

**Problem 2:**

And, 0.225 g of Magnesium metal in 301 seconds from a solution that contains \( Mg^{2+} \) ions?

\[ \boxed{\text{A}} \]

### Explanation

These problems require the use of Faraday's laws of electrolysis to solve for the time or current needed to deposit a certain amount of metal from a solution.

#### Problem 1: Steps for Solution
1. **Calculate the moles of Cadmium deposited:**
   - Molar Mass of \(Cd\): 112.4 g/mol
   - Moles of Cd \((n)\): \(\frac{0.285 \text{ g}}{112.4 \text{ g/mol}}\)

2. **Calculate the total charge (Q) used:**
   - \(Cd^{2+}\) ions require 2 moles of electrons per mole of \(Cd\) deposited.
   - Faraday's constant (\(F\)): 96485 C/mol
   - Total charge (C): \(n \times 2 \times F\)

3. **Calculate time required:**
   - Current (I): 0.105 A
   - Time (t): \(\frac{Q}{I}\)

#### Problem 2: Steps for Solution
1. **Calculate the moles of Magnesium deposited:**
   - Molar Mass of \(Mg\): 24.3 g/mol
   - Moles of Mg \((n)\): \(\frac{0.225 \text{ g}}{24.3 \text{ g/mol}}\)

2. **Calculate the total charge (Q) used:**
   - \(Mg^{2+}\) ions require 2 moles of electrons per mole of \(Mg\) deposited.
   - Faraday's constant (\(F\)): 96485 C/mol
   - Total charge (C): \(n \times 2 \times F\)

3. **Calculate current (I):**
   - Time (t): 301 s
   - Current
Transcribed Image Text:### Electrochemistry Calculation Problems **Problem 1:** How many seconds are required to deposit 0.285 g of Cadmium metal from a solution that contains \( Cd^{2+} \) ions if a current of 0.105 A is applied? \[ \boxed{\text{___} \text{S}} \] **Problem 2:** And, 0.225 g of Magnesium metal in 301 seconds from a solution that contains \( Mg^{2+} \) ions? \[ \boxed{\text{A}} \] ### Explanation These problems require the use of Faraday's laws of electrolysis to solve for the time or current needed to deposit a certain amount of metal from a solution. #### Problem 1: Steps for Solution 1. **Calculate the moles of Cadmium deposited:** - Molar Mass of \(Cd\): 112.4 g/mol - Moles of Cd \((n)\): \(\frac{0.285 \text{ g}}{112.4 \text{ g/mol}}\) 2. **Calculate the total charge (Q) used:** - \(Cd^{2+}\) ions require 2 moles of electrons per mole of \(Cd\) deposited. - Faraday's constant (\(F\)): 96485 C/mol - Total charge (C): \(n \times 2 \times F\) 3. **Calculate time required:** - Current (I): 0.105 A - Time (t): \(\frac{Q}{I}\) #### Problem 2: Steps for Solution 1. **Calculate the moles of Magnesium deposited:** - Molar Mass of \(Mg\): 24.3 g/mol - Moles of Mg \((n)\): \(\frac{0.225 \text{ g}}{24.3 \text{ g/mol}}\) 2. **Calculate the total charge (Q) used:** - \(Mg^{2+}\) ions require 2 moles of electrons per mole of \(Mg\) deposited. - Faraday's constant (\(F\)): 96485 C/mol - Total charge (C): \(n \times 2 \times F\) 3. **Calculate current (I):** - Time (t): 301 s - Current
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