How do polar protic solvents affect nucleophilicity?

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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How do polar protic solvents affect nucleophilicity?

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Introduction

 

Nucleophile - a molecule or substance that has a tendency to donate electrons or react at electron-poor sites such as protons.  When using protic solvents, nucleophilicity does not follow basicity when moving up and down a column. In fact, it's the exact opposite: when basicity decreases, nucleophilicity increases and when basicity increases, nucleophilicity decreases.

 

 

 

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