Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Show the mechanisms of the reactions below

The image displays a chemical reaction mechanism involving two compounds:

1. **Reactant**: A cyclopentanone with an alcohol group (hydroxyl group, OH) attached. The structure features a five-membered ring with a ketone group (C=O) adjacent to an OH group.

2. **Reagents**: 
   - Step 1: NaNH₂ (Sodium amide)
   - Step 2: H⁺ (Proton source, typically an acid)

3. **Product**: The product is an alkyne, specifically a terminal alkyne with the structure depicted as a triple bond (C≡C) at the end of a straight chain.

**Reaction Explanation**:
- The reaction involves the conversion of a ketone-alcohol compound into an alkyne.
- In the first step, the cyclopentanone reacts with sodium amide (NaNH₂), which likely acts as a strong base to deprotonate the hydroxyl group, facilitating elimination.
- In the second step, the introduction of a proton (H⁺) might assist in stabilizing the resulting structure or completing the elimination process, leading to the formation of the alkyne.

This reaction illustrates a typical transformation in organic chemistry where a ketone is converted to an alkyne through the use of a strong base and acid in subsequent steps.
Transcribed Image Text:The image displays a chemical reaction mechanism involving two compounds: 1. **Reactant**: A cyclopentanone with an alcohol group (hydroxyl group, OH) attached. The structure features a five-membered ring with a ketone group (C=O) adjacent to an OH group. 2. **Reagents**: - Step 1: NaNH₂ (Sodium amide) - Step 2: H⁺ (Proton source, typically an acid) 3. **Product**: The product is an alkyne, specifically a terminal alkyne with the structure depicted as a triple bond (C≡C) at the end of a straight chain. **Reaction Explanation**: - The reaction involves the conversion of a ketone-alcohol compound into an alkyne. - In the first step, the cyclopentanone reacts with sodium amide (NaNH₂), which likely acts as a strong base to deprotonate the hydroxyl group, facilitating elimination. - In the second step, the introduction of a proton (H⁺) might assist in stabilizing the resulting structure or completing the elimination process, leading to the formation of the alkyne. This reaction illustrates a typical transformation in organic chemistry where a ketone is converted to an alkyne through the use of a strong base and acid in subsequent steps.
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