HNO3 .NO2 H2SO4, ACOH, 0°C

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Reaction #1: Nitration of benzene
HNO3
NO2
H2SO4, ACOH, 0°C
0 min
30 min
60 min 90 _min .
_120 min| 150 min
| 180 min
210 min
..
..
NA
NA
NA
- +---- - + --
E- + --- - +--
+ --I- -+--
F- + --- - + --
- +--|-
SCRL SCR
S CR
|sCR s CR
sCR s CRL sC R
2H
2H
t
d
1H
t
9.
8
7
6.
4
PPM
3
2
1
1
HNO3
NO2
H2SO4, ACOH, 0°C
Mass used
Theoretical
Mass obtained
Major Product
(grams)
yield (grams)
(grams)
Nitrating agent is in
slight excess
NO2
2.0
1.75
Moles used
Moles
Yield (%)
(mol)
expected (mol)
Nitrating agent is in
slight excess
Relative Reactivity
(1=fastest; 6=slowest)
1 In TLC's, S=starting material; C=Co Spot (mixture of starting material and reaction mixture); R=reaction mixture
Transcribed Image Text:Reaction #1: Nitration of benzene HNO3 NO2 H2SO4, ACOH, 0°C 0 min 30 min 60 min 90 _min . _120 min| 150 min | 180 min 210 min .. .. NA NA NA - +---- - + -- E- + --- - +-- + --I- -+-- F- + --- - + -- - +--|- SCRL SCR S CR |sCR s CR sCR s CRL sC R 2H 2H t d 1H t 9. 8 7 6. 4 PPM 3 2 1 1 HNO3 NO2 H2SO4, ACOH, 0°C Mass used Theoretical Mass obtained Major Product (grams) yield (grams) (grams) Nitrating agent is in slight excess NO2 2.0 1.75 Moles used Moles Yield (%) (mol) expected (mol) Nitrating agent is in slight excess Relative Reactivity (1=fastest; 6=slowest) 1 In TLC's, S=starting material; C=Co Spot (mixture of starting material and reaction mixture); R=reaction mixture
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