Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA E ?
Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA E ?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
9
Transcribed Image Text:Please predict the outcome of each reaction below:
Type you answer as a letter: A, B,..... or F.
Problem 1: https://doi.org/10.1021/cl101705
Answer to Problem 1:
Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond.
Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
Answer to Problem 2:
Problem 2: https://doi.org/10.1016/S0040-4039(00)76159-4
Answer to Problem 3:
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
A
HO,
A
C
D
HỌ
HQ H
HQ H
НО H
H
HO
HO"
HO
HO
強強強強
H
H H
Problem 3: https://doi.org/10.1021/j-9093988
H CO₂Me
Answer to Problem 4:
Me
OSO
A
1 equivalent
m-CPBA
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
H CO₂Me
?
H
E
HO H
H
HO
Me
Ph
B
Ph
Problem 4:https://doi.org/10.1021/j-00341a077
B
H Ph
B
H CO-M
E
?
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
B
Me o
HO H
H₂
?
F
H H
HO.
Me
Ph
Ph
H₂
PIO₂
HO
1. BH₁
2. H₂O₂
HO.
Me
НО
с
H CO₂Me
Me
C
H
H
C
?
F
Ph
Ph
D
HO.
Me
HCO Me
D
HO H
Н.
Me o
H
H
Ph
Ph
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