9 Please predict the outcome of each reaction below:Type you answer as a letter: A, B,..... or F.Problem 1: https://doi.org/10.1021/cl101705Answer to Problem 1:Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond.Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.Answer to Problem 2:Problem 2: https://doi.org/10.1016/S0040-4039(00)76159-4Answer to Problem 3:Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.AHO,ACDHỌHQ HHQ HНО HHHOHO"HOHO強強強強HH HProblem 3: https://doi.org/10.1021/j-9093988H CO₂MeAnswer to Problem 4:MeOSOA1 equivalentm-CPBAHint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.H CO₂Me?HEHO HHHOMePhBPhProblem 4:https://doi.org/10.1021/j-00341a077BH PhBH CO-ME?Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.BMe oHO HH₂?FH HHO.MePhPhH₂PIO₂HO1. BH₁2. H₂O₂HO.MeНОсH CO₂MeMeCHHC?FPhPhDHO.MeHCO MeDHO HН.Me oHHPhPh

Since you have posted multiple questions, we will provide the solution only to the first question as…

Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA E ?

Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond. Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer. 1 equivalent m-CPBA E ?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

Please predict the outcome of each reaction below:
Type you answer as a letter: A, B,..... or F.
Problem 1: https://doi.org/10.1021/cl101705
Answer to Problem 1:
Hint 1. Assume the reaction can ONLY occur at the MOST ELECTRON RICH double bond.
Hint 2. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
Answer to Problem 2:
Problem 2: https://doi.org/10.1016/S0040-4039(00)76159-4
Answer to Problem 3:
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
A
HO,
A
C
D
HỌ
HQ H
HQ H
НО H
H
HO
HO"
HO
HO
強強強強
H
H H
Problem 3: https://doi.org/10.1021/j-9093988
H CO₂Me
Answer to Problem 4:
Me
OSO
A
1 equivalent
m-CPBA
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
H CO₂Me
?
H
E
HO H
H
HO
Me
Ph
B
Ph
Problem 4:https://doi.org/10.1021/j-00341a077
B
H Ph
B
H CO-M
E
?
Hint. Assume the reaction can ONLY occur from the least sterically hindered side of the molecule. Draw or build a 3-dimentional conformation to support your answer.
B
Me o
HO H
H₂
?
F
H H
HO.
Me
Ph
Ph
H₂
PIO₂
HO
1. BH₁
2. H₂O₂
HO.
Me
НО
с
H CO₂Me
Me
C
H
H
C
?
F
Ph
Ph
D
HO.
Me
HCO Me
D
HO H
Н.
Me o
H
H
Ph
Ph

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