Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
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1. A canister containing air has a volume of 85 cm’ and a pressure of 1.45 atm when the temperature is 310 K.
What is the pressure when the volume is increased to 180 cm’ and the temperature is reduced to 280 K?
2. Air is transferred from a 75 L tank where the pressure is 125 psi and the temperature is 288 K to a tire with a
volume of 6.1 L and a pressure of 25 psi. What is the new temperature?
3. A helium balloon at 28°C has a volume of 1.8 L and a pressure of 102 kPa. What is the volume of the
balloon when is rises into the atmosphere where the pressure is 85 kPa and the temperature is 4°C?
4. The pressure of a piston with a volume of 650 cm' and 85°C is 830 torr. It is be ated to 350°C and
compressed to a volume of 65 cm'. What is the new pressure?
5. A gas tank has a volume of 28.1 m' and a pressure of 18.4 atm. The temperature of the gas is 32°C. What is
the Celsius temperature when the gas is put in an 11.2 m' tank with a pressure of 22.7 atm?
6. A metal can is able to withstand 3800 kPa before is bursts. The gas in the can has a volume of 235 mL and
the pressure is 110 kPa at 25°C, If the can Is crushed to a volume of 8.5 mL and the temperature does not
change will it burst? What is the pressure of the
gas
in
the can?
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