HCI(g) can be synthesized from H,(g) and Cl,(g) as represented above. A student studying the kinetics of the reaction proposes the following mechanism. AH = 242 kJ/mol, AH = 4 kJ/mol, -432 kJ/mol, 2 Cl(g) (slow) Step 1: Cl,(g) Step 2: H,(g) + CI(g) HCI(g) + H(g) Step 3: H(g) + Cl(g) HCI(g) (fast) (fast) AH 42. Which of the following statements identifies the greatest single reason that the value of K, for the overall reaction at 298 K has such a large magnitude? (A) The activation energy for step I of the mechanism is large and positive. (B) The activation energy for step 2 of the mechanism is small and positive. (C) The value of AS for the overall reaction is small and positive. (D) The value of AH° for the overall reaction is large and negative.

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H,(g) + Cl,(g) 2 HCI(g)
K, = 2 x 1030 at 298 K
HCI(g) can be synthesized from H,(g) and Cl,(g) as represented above. A student studying the kinetics of the
reaction proposes the following mechanism.
Step 1: Cl(g) 2 Cl(g)
Step 2: H,(g) + Cl(g) HCI(g) + H(g)
AH° = 242 kJ/mol,
(slow)
(fast)
(fast)
AH
4 kJ/mol,
-432 kJ/mol
%3D
Step 3: H(g) + CI(g)
HCI(g)
AH° =
42. Which of the following statements identifies the
greatest single reason that the value of K, for the
overall reaction at 298 K has such a large
magnitude?
(A) The activation energy for step I of the
mechanism is large and positive.
(B) The activation energy for step 2 of the
mechanism is small and positive.
(C) The value of AS for the overall reaction is
small and positive.
(D) The value of AH° for the overall reaction is
large and negative.
Transcribed Image Text:H,(g) + Cl,(g) 2 HCI(g) K, = 2 x 1030 at 298 K HCI(g) can be synthesized from H,(g) and Cl,(g) as represented above. A student studying the kinetics of the reaction proposes the following mechanism. Step 1: Cl(g) 2 Cl(g) Step 2: H,(g) + Cl(g) HCI(g) + H(g) AH° = 242 kJ/mol, (slow) (fast) (fast) AH 4 kJ/mol, -432 kJ/mol %3D Step 3: H(g) + CI(g) HCI(g) AH° = 42. Which of the following statements identifies the greatest single reason that the value of K, for the overall reaction at 298 K has such a large magnitude? (A) The activation energy for step I of the mechanism is large and positive. (B) The activation energy for step 2 of the mechanism is small and positive. (C) The value of AS for the overall reaction is small and positive. (D) The value of AH° for the overall reaction is large and negative.
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