HBr, (t-BuO)2

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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Predict the products of the following reaction

The image depicts a chemical reaction. The starting material is isobutylene. It undergoes a reaction with hydrogen bromide (HBr) in the presence of tert-butyl peroxide ((t-BuO)₂) as a radical initiator. This setup suggests a free radical addition reaction, which typically results in the anti-Markovnikov addition of HBr to the double bond in isobutylene. The reaction involves the formation of a bromine radical that adds to the less substituted carbon atom of the double bond.
Transcribed Image Text:The image depicts a chemical reaction. The starting material is isobutylene. It undergoes a reaction with hydrogen bromide (HBr) in the presence of tert-butyl peroxide ((t-BuO)₂) as a radical initiator. This setup suggests a free radical addition reaction, which typically results in the anti-Markovnikov addition of HBr to the double bond in isobutylene. The reaction involves the formation of a bromine radical that adds to the less substituted carbon atom of the double bond.
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