H3C 1. NaN3 2. H₂O, heat H3C CI Acid chlorides can be converted into primary amines with the loss of a single carbon atom via the Curtius rearrangement. The reaction involves treating an acid chloride with sodiur azide to form an acyl azide. The acyl azide then loses N₂ to give an isocyanate, which is hydrolyzed to release CO₂ and the primary amine. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions →X™ NH H :A CH3NH2 + CO₂ H-A N₂ + NaCl HạC—NH, CO₂ H-A :A

H3C 1. NaN3 2. H₂O, heat H3C CI Acid chlorides can be converted into primary amines with the loss of a single carbon atom via the Curtius rearrangement. The reaction involves treating an acid chloride with sodiur azide to form an acyl azide. The acyl azide then loses N₂ to give an isocyanate, which is hydrolyzed to release CO₂ and the primary amine. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions →X™ NH H :A CH3NH2 + CO₂ H-A N₂ + NaCl HạC—NH, CO₂ H-A :A

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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