H (c) -N-H H (2) C (b) one - The bond labeled (a) forms from o-overlap of a C sp2 ▾ orbital and a H 1s The bond labeled (b) forms from: • one o-overlap of a C π-overlap (s) of a C orbital and a N The bond labeled (c) forms from O orbital and a N overlap of a N orbital, and The ideal bond angle <(C-N-H) around the N atom is orbital. orbital and a H 1s There is/are one lone pair(s) around the N atom. Lewis structures do not attempt to portray 3D shape, but you can predict the molecular geometry from VSEPR theory. The ideal bond angle <(H-C-H) around the C atom is 120 degrees. orbital. degrees. orbital.

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Chapter1: Chemical Foundations
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Valence bond theory
The skeletal structure for methyleneimine (CH₂NH) is shown. Draw for yourself the best Lewis
structure. Propose a bonding scheme by indicating the hybridization of the central atoms and the
orbital overlaps for each bond.
(a)
H
one
(b)
H-C-N-H
The bond labeled (a) forms from
The bond labeled (b) forms from:
● one o-overlap of a C
(c)
π-overlap (s) of a C
-overlap of a C sp2
orbital and a N
orbital and a N
orbital and a H 1s
The ideal bond angle <(C-N-H) around the N atom is
orbital, and
orbital.
The bond labeled (c) forms from O - overlap of a N
There is/are one lone pair(s) around the N atom.
Lewis structures do not attempt to portray 3D shape, but you can predict the molecular geometry from
VSEPR theory.
The ideal bond angle <(H-C-H) around the C atom is 120
orbital and a H 1s
degrees.
orbital.
degrees.
orbital.
Transcribed Image Text:Valence bond theory The skeletal structure for methyleneimine (CH₂NH) is shown. Draw for yourself the best Lewis structure. Propose a bonding scheme by indicating the hybridization of the central atoms and the orbital overlaps for each bond. (a) H one (b) H-C-N-H The bond labeled (a) forms from The bond labeled (b) forms from: ● one o-overlap of a C (c) π-overlap (s) of a C -overlap of a C sp2 orbital and a N orbital and a N orbital and a H 1s The ideal bond angle <(C-N-H) around the N atom is orbital, and orbital. The bond labeled (c) forms from O - overlap of a N There is/are one lone pair(s) around the N atom. Lewis structures do not attempt to portray 3D shape, but you can predict the molecular geometry from VSEPR theory. The ideal bond angle <(H-C-H) around the C atom is 120 orbital and a H 1s degrees. orbital. degrees. orbital.
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