Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group and form chelate ringsbonded through both the N and one of the O atoms. Draw structures for all possible isomers of tris(glycinato)cobalt(III).

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3. Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group
and form chelate ringsbonded through both the N and one of the O atoms. Draw
structures for all possible isomers of tris(glycinato)cobalt(III).
4. Sketch structures of all isomers of M(AB)3, in which ABis a bidentate unsymmetrical
ligand, and label the structuresfacor mer.
5. Sketch all isomers of the following. Indicate clearly eachpair of enantiomers.
i. [PI(NH;);Cls]"
ii. [Co(NH,);(H,O),CH]*
iii. [Co(NH,):(H;0),BICI)
iv. [CrH,O),BrCin
v. [Pt(en):Cla)**
vi. [Pt(bipy),BrC1}*
How many possible isomers are there of an octahedral complex having the formula
M(ABC)(NH,H;O)Br, where ABC is the tridentate ligand
H,N-C,H,-PH-C,H-ASH2? How many of these consist of pairs of enantiomers?
Sketch all isomers, showing clearly any pairs of enantiomers. The tridentate ligand may
be abbreviated as N-P-As for simplicity.
Transcribed Image Text:3. Glycine has the structure NH;CH;COOH. It can lose aproton from the carboxyl group and form chelate ringsbonded through both the N and one of the O atoms. Draw structures for all possible isomers of tris(glycinato)cobalt(III). 4. Sketch structures of all isomers of M(AB)3, in which ABis a bidentate unsymmetrical ligand, and label the structuresfacor mer. 5. Sketch all isomers of the following. Indicate clearly eachpair of enantiomers. i. [PI(NH;);Cls]" ii. [Co(NH,);(H,O),CH]* iii. [Co(NH,):(H;0),BICI) iv. [CrH,O),BrCin v. [Pt(en):Cla)** vi. [Pt(bipy),BrC1}* How many possible isomers are there of an octahedral complex having the formula M(ABC)(NH,H;O)Br, where ABC is the tridentate ligand H,N-C,H,-PH-C,H-ASH2? How many of these consist of pairs of enantiomers? Sketch all isomers, showing clearly any pairs of enantiomers. The tridentate ligand may be abbreviated as N-P-As for simplicity.
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