Glycerol (1,2,3-propanetriol) is by-product of converting waste fats (triglycerides) into bio-diesel. Glycerol ОН HO HO I Vapor pressure of liquid P in mm Hg 1 10 40 100 400 760 T in °C 125.5 167.2 198.0 220.1 263.0 290.0 It has a melting point of 17.8 C. Write the equilibrium expression for the vapor pressure over the pure liquid a. C3H8O2(liquid) = C3H&O2(gas) %3! That is, K = ? b. Estimate its vapor pressure over the pure liquid at 20 C. Remember, -RT Ink = AG = AH - TAS, and for AH constant, the van't Hoff equation applies In(K:/K1) = AH/R (1/T: - 1/T)

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Chapter1: Chemical Foundations
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Glycerol (1,2,3-propanetriol) is by-product of converting waste fats (triglycerides) into bio-diesel.
Glycerol
ОН
HO
HO
Vapor pressure of liquid
P in mm Hg 1
10
40
100
400
760
T in °C
125.5 167.2 198.0 220.1 263.0 290.0
It has a melting point of 17.8 C.
a. Write the equilibrium expression for the vapor pressure over the pure liquid
C3H8O2(liquid) = C3H&O2(gas)
That is,
K= ?
b.
Estimate its vapor pressure over the pure liquid at 20 C. Remember,
-RT Ink = AG = AH - TAS, and for AH constant, the van't Hoff equation applies
In(K:/K1) = AH/R (1/T - 1/T)
Transcribed Image Text:Glycerol (1,2,3-propanetriol) is by-product of converting waste fats (triglycerides) into bio-diesel. Glycerol ОН HO HO Vapor pressure of liquid P in mm Hg 1 10 40 100 400 760 T in °C 125.5 167.2 198.0 220.1 263.0 290.0 It has a melting point of 17.8 C. a. Write the equilibrium expression for the vapor pressure over the pure liquid C3H8O2(liquid) = C3H&O2(gas) That is, K= ? b. Estimate its vapor pressure over the pure liquid at 20 C. Remember, -RT Ink = AG = AH - TAS, and for AH constant, the van't Hoff equation applies In(K:/K1) = AH/R (1/T - 1/T)
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