Given the reduction potentials below:Reduction Half-ReactionE° (V) Reduction Half-ReactionE° (V)F2(g)+2e− → 2F−(aq)+2.87 Pb2+(aq)+2e− → Pb(s)-0.13Cl2(l)+2e− → 2Cl− (aq)+1.36 Sn2+(aq)+2e− → Sn(s)-0.14O2(g)+4H+(aq)+4e− → 2H2O(l)+1.23 Ni2+(aq)+2e− → Ni(s)-0.23Br2(l)+2e− → 2Br−(aq)+1.09 V3+(aq)+e− → V2+(aq)-0.26Ag+(aq)+e− → Ag(s)+0.80 Cd2+(aq)+2e− → Cd(s)-0.40Fe3+(aq)+e− → Fe2+(aq)+0.77 Fe2+(aq)+2e− → Fe(s)-0.44I2(l) + 2e− → 2I−(aq)+0.54 Cr3+(aq)+3e− → Cr(s)-0.74Cu2+(aq)+2e− → Cu(s)+0.34 Zn2+(aq)+2e− → Zn(s)-0.76Sn4+(aq)+2e− → Sn2+(aq)+0.15 Mn2+(aq)+2e− → Mn(s)-1.182H+(aq)+2e− → H2(g)0.00 Al3+(aq)+3e− → Al(s)-1.66 What is the value of ΔGo in kJ at 25 oC for the reaction between the pair: Ag(s) and Mn2+(aq) to give Mn(s) and Ag+(aq) ?

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Answered: Given the reduction potentials below:…

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter19: Principles Of Chemical Reactivity: Electron Transfer Reactions

Section: Chapter Questions

Problem 90GQ: Use the table of standard reduction potentials (Appendix M) to calculate rG for the following...

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Given the reduction potentials below:

Reduction Half-Reaction	E° (V)	Reduction Half-Reaction	E° (V)
F₂(g)+2e⁻ → 2F⁻(aq)	+2.87	Pb²⁺(aq)+2e⁻ → Pb(s)	-0.13
Cl₂(l)+2e⁻ → 2Cl⁻ (aq)	+1.36	Sn²⁺(aq)+2e⁻ → Sn(s)	-0.14
O₂(g)+4H⁺(aq)+4e⁻ → 2H₂O(l)	+1.23	Ni²⁺(aq)+2e⁻ → Ni(s)	-0.23
Br₂(l)+2e⁻ → 2Br⁻(aq)	+1.09	V³⁺(aq)+e⁻ → V²⁺(aq)	-0.26
Ag⁺(aq)+e⁻ → Ag(s)	+0.80	Cd²⁺(aq)+2e⁻ → Cd(s)	-0.40
Fe³⁺(aq)+e⁻ → Fe²⁺(aq)	+0.77	Fe²⁺(aq)+2e⁻ → Fe(s)	-0.44
I₂(l) + 2e⁻ → 2I⁻(aq)	+0.54	Cr³⁺(aq)+3e⁻ → Cr(s)	-0.74
Cu²⁺(aq)+2e⁻ → Cu(s)	+0.34	Zn²⁺(aq)+2e⁻ → Zn(s)	-0.76
Sn⁴⁺(aq)+2e⁻ → Sn²⁺(aq)	+0.15	Mn²⁺(aq)+2e⁻ → Mn(s)	-1.18
2H⁺(aq)+2e⁻ → H₂(g)	0.00	Al³⁺(aq)+3e⁻ → Al(s)	-1.66

What is the value of ΔG^o in kJ at 25 ^oC for the reaction between the pair:

Ag(s) and Mn²⁺(aq) to give Mn(s) and Ag⁺(aq) ?

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