Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p peak for S is further to the right than the 3p peak for P? 135
Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p peak for S is further to the right than the 3p peak for P? 135
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Relative Number of Electrons
8. Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following
best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p
peak for S is further to the right than the 3p peak for P?
Relative Number of Electrons
1000
1000
208
239
100
100
135
18.7
16.5
22.7
10
Due: Wed., 3/1/23
10
Binding Energy
1.95
2.05
1.06
1.00
1
Phosphorus
P
0.1 MJ/mol
Sulfur
S
AP Chemistry
6.1 MJ/mol
(A) S has a greater effective nuclear charge than P, and the 3p sublevel in S has greater electron
repulsions than in P.
(B) S has a greater effective nuclear charge than P, and the 3p sublevel is more heavily shielded
in S than in P.
I
(C) S has a greater number of electrons than P, so the third energy level is further from the
nucleus in S than in P.
(D) S has a greater number of electrons than P, so the Coulombic attraction between the electron
cloud and the nucleus is greater in S than in P."
Transcribed Image Text:Name:
Relative Number of Electrons
8. Given the photoelectron spectra below for phosphorus, P, and sulfur, S, which of the following
best explains why the 2p peak for S is further to the left than the 2p peak for P, but the 3p
peak for S is further to the right than the 3p peak for P?
Relative Number of Electrons
1000
1000
208
239
100
100
135
18.7
16.5
22.7
10
Due: Wed., 3/1/23
10
Binding Energy
1.95
2.05
1.06
1.00
1
Phosphorus
P
0.1 MJ/mol
Sulfur
S
AP Chemistry
6.1 MJ/mol
(A) S has a greater effective nuclear charge than P, and the 3p sublevel in S has greater electron
repulsions than in P.
(B) S has a greater effective nuclear charge than P, and the 3p sublevel is more heavily shielded
in S than in P.
I
(C) S has a greater number of electrons than P, so the third energy level is further from the
nucleus in S than in P.
(D) S has a greater number of electrons than P, so the Coulombic attraction between the electron
cloud and the nucleus is greater in S than in P.
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