Given the following information: Bond C-H C-S S-H S=S Bond energy (kJ/mol) 414 259 347 452 Enthalpy of sublimation of CH3SH is 32.40 kJ/mol. (a) Estimate AH° in kJ for the formation of gaseous CH3SH in the following reaction: 2 CH4 (g) + S2 (g) ---> 2 CH;SH (g) Answer: kJ (b) Estimate AH° in kJ for the decomposition of solid CH3SH. 2 CH3SH (s) ---> 2 CH4 (g) + S2 (g) Answer: kJ

Given the following information: Bond C-H C-S S-H S=S Bond energy (kJ/mol) 414 259 347 452 Enthalpy of sublimation of CH3SH is 32.40 kJ/mol. (a) Estimate AH° in kJ for the formation of gaseous CH3SH in the following reaction: 2 CH4 (g) + S2 (g) ---> 2 CH;SH (g) Answer: kJ (b) Estimate AH° in kJ for the decomposition of solid CH3SH. 2 CH3SH (s) ---> 2 CH4 (g) + S2 (g) Answer: kJ

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter6: Covalent Bonding

Section: Chapter Questions

Problem 35QRT

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Concept explainers

Thermochemistry

Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.

Exergonic Reaction

The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.

Question

Given the following information:
Bond
C-H
C-S
S-H
S=S
Bond energy (kJ/mol)
414
259
347
452
Enthalpy of sublimation of CH3SH is 32.40 kJ/mol.
(a) Estimate AH° in kJ for the formation of gaseous CH3SH in the following reaction:
2 CH4 (g) +
S2 (g)
---> 2 CH3SH (g)
Answer:
kJ
(b) Estimate AH° in kJ for the decomposition of solid CH3SH.
2 CH3SH (s) ---> 2 CH4 (g) + S2 (g)
Answer:
kJ

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