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Give the equation for the quantum yield for the path that has T2, 02. (Use the following as necessary: T, T1, T2, and T3.) Calculate the quantum yield, 2, with the given values. (Enter an unrounded value with at least 3 digits.)

Give the equation for the quantum yield for the path that has T2, 02. (Use the following as necessary: T, T1, T2, and T3.) Calculate the quantum yield, 2, with the given values. (Enter an unrounded value with at least 3 digits.)

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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rate of ith decay mechanism rate of removal of the singlet state rate of ith decay mechanism rate of formation of the singlet state rate of removal of the singlet state rate of ith decay mechanism Step 4 of 6 Give the quantum yield j. (Use the following as necessary: kj, k1, k2, k3, and t.) k; k1 + k, + k ki 3 ki + k2 + k3 Recalling the relationship between the overall rate constant, k, and the mean lifetime, T, give the quantum yield ¢; in terms of t and Tj. (Use the following as necessary: T and T;) O; = i Step 5 of 6 (c) If T1 = 1×10-7 s, Tɔ = 4×10-8 s, and T3 = 1×10-8 s, calculate the lifetime of the singlet state and the quantum yield for the path that has Tɔ. (Enter an unrounded value with at least 3 digits.) Calculate using the equation given in (b). 1 135e6 135000000 s-1 Solve for T, the lifetime of the singlet state. T = |7.407e-9 7.40740740740741e-09 s Step 6 of 6 Give the equation for the quantum yield for the path that has T2, P2. (Use the following as necessary: T, T1, T2, and T3.) P2 = Calculate the quantum yield, P2, with the given values. (Enter an unrounded value with at least 3 digits.)
Transcribed Image Text:rate of ith decay mechanism rate of removal of the singlet state rate of ith decay mechanism rate of formation of the singlet state rate of removal of the singlet state rate of ith decay mechanism Step 4 of 6 Give the quantum yield j. (Use the following as necessary: kj, k1, k2, k3, and t.) k; k1 + k, + k ki 3 ki + k2 + k3 Recalling the relationship between the overall rate constant, k, and the mean lifetime, T, give the quantum yield ¢; in terms of t and Tj. (Use the following as necessary: T and T;) O; = i Step 5 of 6 (c) If T1 = 1×10-7 s, Tɔ = 4×10-8 s, and T3 = 1×10-8 s, calculate the lifetime of the singlet state and the quantum yield for the path that has Tɔ. (Enter an unrounded value with at least 3 digits.) Calculate using the equation given in (b). 1 135e6 135000000 s-1 Solve for T, the lifetime of the singlet state. T = |7.407e-9 7.40740740740741e-09 s Step 6 of 6 Give the equation for the quantum yield for the path that has T2, P2. (Use the following as necessary: T, T1, T2, and T3.) P2 = Calculate the quantum yield, P2, with the given values. (Enter an unrounded value with at least 3 digits.)
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