Gasoline is a complex mixture of hydrocarbons, including different isomers of octane. Gasoline is sold with a variety of octane ratings that are based on the comparison of the gasoline with the combustion properties of isooctane, a structural isomer of CgH18. The structure of isooctane and another isomer of CgH18 are shown in the figure below, along with their normal boiling points and heats of vaporization. Determine the vapor pressure of each isomer on a very hot summer day, 39.0°C. Price per gallon All tanes inluded Price per gallon All taes included Price per gallon All taxes included INIMUM OCTANE RATING MINIMUM OCTANE RATING MLUSMETHOO INIMUM OCTANE RATING IM METHOO ( METHOO 87 89 93 PRESS PRESS PRESS Image credit: Stephen VanHorn/Shutterstock Isooctane Tetramethylbutane bp = 98.2°C bn - 104 FRC

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Gasoline is a complex mixture of hydrocarbons, including different isomers of octane. Gasoline is sold with a variety of octane ratings that are
based on the comparison of the gasoline with the combustion properties of isooctane, a structural isomer of CgH18. The structure of isooctane
and another isomer of CgH18 are shown in the figure below, along with their normal boiling points and heats of vaporization. Determine the
vapor pressure of each isomer on a very hot summer day, 39.0°C.
Price per gallon
All taxes included
Price per gallon
All taxes included
Price per gallon
All taxes included
MINIMUM OCTANE RATING
NINIMUM OCTANE RATING
aNIMUM OCTANE RATING
(R-M)/2 METHOO
(R.M)/ METHOO
(A.u)2 METHOD
87
89
93
PRES S
PRESS
PRESS
Image credit: Stephen VanHorn/Shutterstock
Isooctane
Tetramethylbutane
bp = 98.2°C
bp = 106 5°C
Transcribed Image Text:Gasoline is a complex mixture of hydrocarbons, including different isomers of octane. Gasoline is sold with a variety of octane ratings that are based on the comparison of the gasoline with the combustion properties of isooctane, a structural isomer of CgH18. The structure of isooctane and another isomer of CgH18 are shown in the figure below, along with their normal boiling points and heats of vaporization. Determine the vapor pressure of each isomer on a very hot summer day, 39.0°C. Price per gallon All taxes included Price per gallon All taxes included Price per gallon All taxes included MINIMUM OCTANE RATING NINIMUM OCTANE RATING aNIMUM OCTANE RATING (R-M)/2 METHOO (R.M)/ METHOO (A.u)2 METHOD 87 89 93 PRES S PRESS PRESS Image credit: Stephen VanHorn/Shutterstock Isooctane Tetramethylbutane bp = 98.2°C bp = 106 5°C
bp = 98.2°C
bp = 106.5°C
%3D
AHvap = 35.8 kJ/mol
AHvap= 43.3 kJ/mol
%3D
1st attempt
Part 1
See Periodic Table See Hint
1 atm 760 torr
For isooctane:
torr
Part 2
See Hint
For tetramethylbutane:
torr
Transcribed Image Text:bp = 98.2°C bp = 106.5°C %3D AHvap = 35.8 kJ/mol AHvap= 43.3 kJ/mol %3D 1st attempt Part 1 See Periodic Table See Hint 1 atm 760 torr For isooctane: torr Part 2 See Hint For tetramethylbutane: torr
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