Gaseous SO2Cl2 reacts with liquid water to form hydrogen chloride gas and liquid sulfuric acid. Using data tabulated in Appendix G of your text, calculate the enthalpy change, in units of kJ/mol, for the formation of 2 mol of liquid sulfuric acid.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Gaseous SO2Cl2 reacts with liquid water to form hydrogen chloride gas and liquid sulfuric acid. Using data tabulated in Appendix G of your text, calculate the enthalpy change, in units of kJ/mol, for the formation of 2 mol of liquid sulfuric acid. |
![(kJ mol)
AG; (kJ mol-1)
S° (JK-ª mol-3)
Substance
AsCla(g)
-261.50
-248.95
327.06
As2S3(s)
-169.03
-168.62
163.59
AsH3(g)
66.44
68.93
222.78
H3ASO.(s)
-906.3
barium
Ba(s)
62.5
Ba(g)
180
146
170.24
Ba?"(aq)
-537.6
-560.8
9.6
BaO(s)
-548.0
-520.3
72.1
Bacl2(s)
-855.0
-806.7
123.7
BasO,(s)
-1473.2
-1362.3
132.2
beryllium
Be(s)
9.50
Be(g)
324.3
286.6
136.27
BeO(s)
-609.4
-580.1
13.8
bismuth
Bi(s)
56.74
Bi(g)
207.1
168.2
187.00
BizO3(s)
-573.88
-493.7
151.5
BiCla(s)
-379.07
-315.06
176.98
BizSa(s)
-143.1
-140.6
200.4
boron
B(s)
5.86
B(g)
565.0
521.0
153.4
B203(s)
-1273.5
-1194.3
53.97
B2He(g)
36.4
87.6
232.1
H3BO3(s)
-1094.33
-968.92
88.83](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F60fd30ad-310c-4c27-b4b7-947d25048219%2Fdb05fc71-92a3-4767-a8ee-0077bda32326%2Fyms9cv8tv_processed.png&w=3840&q=75)
![Standard Thermodynamic Properties for Selected Substances
AH; (kJ mol)
AG; (kJ mol) s° (JKª mol-)
Substance
aluminum
Al(s)
28.3
Al(g)
324.4
285.7
164.54
A"(aq)
-531
-485
-321.7
Al2O3(s)
-1676
-1582
50.92
AIF3(s)
-1510.4
-1425
66.5
AICI3(s)
-704.2
-628.8
110.67
AICI3-6H20(s)
-2691.57
-2269.40
376.56
Al2Sa(s)
-724.0
-492.4
116.9
Al2(SO4)3(s)
-3445.06
-3506.61
239.32
antimony
Sb(s)
45.69
Sb(g)
262.34
222.17
180.16
Sb,Os(s)
-1440.55
-1268.17
220.92
SbCl3(g)
-313.8
-301.2
337.80
SbCls(g)
-394.34
-334.29
401.94
Sb;S3(s)
-174.89
-173.64
182.00
SbCla(s)
-382.17
-323.72
184.10
SBOCI(s)
-374.0
arsenic
As(s)
35.1
As(g)
302.5
261.0
174.21
Asa(g)
143.9
92.4
314
As,O6(s)
-1313.94
-1152.52
214.22
As2Os(s)
-924.87
-782.41
105.44
Telele C1](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F60fd30ad-310c-4c27-b4b7-947d25048219%2Fdb05fc71-92a3-4767-a8ee-0077bda32326%2Fxkl1rs_processed.png&w=3840&q=75)
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