Gas molecules of mass m are confined in a cylinder of radius R and height L (with R >> L) kept vertically in the Earth's gravitational field. The average energy of the gas at low temperatures (such that mgL >> k,T ) is given by
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A: MAr = 40 MKr = 84 Kinetic energy of atom = (3/2)kT = (3/2)(kPV/nR) = (3/2)(kPVMw/mR)
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- You measure the average free path λ and the average collision time τ of the molecules of a diatomic gas of molecular mass 6.00 × 10-²⁵ kg and radius r = 1.0 x 10-¹⁰ m. From these microscopic data can we obtain macroscopic properties such as temperature T and pressure P? If so, consider λ = 4.32 x 10-⁸ m and τ = 3.00 x 10-¹⁰ s and calculate T and P. indicate the correct answer: 1- Not possible2- Yes, T =150 K and P ~ 2.04 atm.3- Yes, T = 150 K and P ~ 4.08 atm.4- Yes, T = 300 K and P ~ 4.08 atm.5- Yes, T = 300 K and P ~ 5.32 atm6- Yes, T = 400 K and P ~ 4.08 atm.7- Yes, T = 400 K and P ~ 5.32 atm. obs.: If necessary, consider: R = 8.314 J/mol∙K1 cal = 4.19 Jkb =1,38 x 10⁻²³ m² kg s⁻² K⁻¹Consider a gas composed of 1 mol of deuterium atoms (molar mass = 2 g/mol) in a 0.025 m³ container at a temperature of 400 K. Using the results of statistical mechanics, calculate the Helmholtz energy of the gas in J.A particle on the surface of the Earth can "escape" the Earth's gravitation and continue to move away from the Earth forever, if it has a sufficient speed (called the escape speed). (a) Determine the escape speed (in m/s) if the particle is an oxygen molecule. Use 6.37 x 106 m for radius of the Earth. m/s (b) Determine the temperature (in K) at which the rms speed of the oxygen molecule is 13 times the escape speed. T = K (c) What If? The Universe is composed of 75% hydrogen and 25% helium by mass, yet these gases are not found in the Earth's atmosphere. Calculate the temperatures (in K) for which the minimum escape kinetic energy is nine times the average kinetic energy of hydrogen (H₂) molecules and helium atoms. K K TH2 THE
- One cylinder contains helium gas (atomic weight = 4.0 g/mol) and another contains argon gas(atomic weight = 40 g/mol) at the same %3D temperature. The average kinetic energies of atoms in the two gases are the same. Select one: True FalseHelium atoms interact very weakly with each other; helium only liquefies at 4.2 K at standardpressure. What is the kinetic energy of a helium atom:(a) at 100. K?(b) at 10.0 K?Three moles of an ideal gas are in a rigid cubical box with sides of length 0.300 m. (a) What is the force that the gas exerts on each of the six sides of the box when the gas temperature is 20.0°C?
- What is the RMS speed (in m/s) of a gas molecule, with mass 4.3x10-26 kg at a temperature of 98 degrees Fahrenheit?The mass of a helium atom is 6.650e–27 kg. What is the average speed of a helium molecule in a monoatomic gas at a temperature of 77 C?Long-term space missions require reclamation of the oxygen in the carbon dioxide exhaled by the crew. In one method of reclamation, 1.00 mol of carbon dioxide produces 1.00 mol of oxygen, with 1.00 mol of methane as a by-product. The methane is stored in a tank under pressure and is available to control the attitude of the spacecraft by controlled venting. A single astronaut exhales 1.21 kg of carbon dioxide each day. If the methane generated in the recycling of three astronauts' respiration during one week of flight is stored in an originally empty 155-L tank at −45.0°C, what is the final pressure in the tank? MPa
- An expensive vacuum system can achieve a pressure as low as 1.00 x 10-9 N/m² at 19.5 °C. How many atoms N are there in a cubic centimeter at this pressure and temperature? The Boltzmann constant k = 1.38 x 10-23 J/K. N = atomsThe distribution function for speeds of particles in an ideal gas can be expressed as |3/2 m -e/k,T ee f(v)=- m 2a kg T Prove that f(v) is maximum for e=kgT where E=-mv |2 kgT From this results, show that the most probable speed is v,=N mTwo moles of a helium gas are at a temperature of 260 K. Calculate the average kinetic energy per atom, the root-mean-square (rms) speed of atoms in the gas, and the internal energy of the gas. HINT (a) the average kinetic energy per atom (in J) J (b) the root-mean-square (rms) speed (in m/s) of atoms in the gas m/s (c) the internal energy of the gas (in J) J