From the choices given below select the L-aldopentose that yields an optically inactive alditol upon reduction with NaBH4- Select ALL monosaccharides that satisfy the requirement, excluding the structure referenced in the question. Note that only D structures are shown. To select an L structure click on the name. If no selection exists, then select the referenced structure. H H H- CHO OH -OH +OH CH₂OH D-Ribose L-Ribose HO H- H- CHO -H -OH -OH CH₂OH D-Arabinose L-Arabinose H HO- H CHO -OH -H -OH CH₂OH D-Xylose L-Xylose HO- HO H- CHO -H -H -OH CH₂OH D-Lyxose L-Lyxose

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Chapter1: Chemical Foundations
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**Chemical Structure Selection Exercise**

**Objective:**  
From the choices given below, select the **L-aldopentose** that yields an **optically inactive alditol** upon reduction with NaBH₄.

**Instructions:**  
- Select **ALL** monosaccharides that satisfy the requirement, excluding the structure referenced in the question. Note that only **D** structures are shown. To select an **L** structure, click on the name.
- **If no selection exists, then select the referenced structure.**

**Structures:**

1. **D-Ribose**  
   - Configuration: CHO–(H–OH)–(H–OH)–(H–OH)–CH₂OH

2. **D-Arabinose**  
   - Configuration: CHO–(H–OH)–(OH–H)–(H–OH)–CH₂OH

3. **D-Xylose**  
   - Configuration: CHO–(H–OH)–(H–OH)–(OH–H)–CH₂OH

4. **D-Lyxose**  
   - Configuration: CHO–(OH–H)–(H–OH)–(H–OH)–CH₂OH

**Names of Corresponding L Structures:**
- **L-Ribose**
- **L-Arabinose**
- **L-Xylose**
- **L-Lyxose**

**Graph/Diagram Explanation:**
The graphical section displays linear structural formulas of four D-aldopentoses, each consisting of five carbon atoms. They are arranged vertically with:
- An aldehyde group (CHO) at the top,
- Three hydroxyl groups (OH) each attached to their respective carbon atoms, which are shown in different stereochemical configurations,
- A terminal CH₂OH group at the bottom.

The configurations indicate the orientation of the hydroxyl groups which are crucial in determining optical activity upon reduction.
Transcribed Image Text:**Chemical Structure Selection Exercise** **Objective:** From the choices given below, select the **L-aldopentose** that yields an **optically inactive alditol** upon reduction with NaBH₄. **Instructions:** - Select **ALL** monosaccharides that satisfy the requirement, excluding the structure referenced in the question. Note that only **D** structures are shown. To select an **L** structure, click on the name. - **If no selection exists, then select the referenced structure.** **Structures:** 1. **D-Ribose** - Configuration: CHO–(H–OH)–(H–OH)–(H–OH)–CH₂OH 2. **D-Arabinose** - Configuration: CHO–(H–OH)–(OH–H)–(H–OH)–CH₂OH 3. **D-Xylose** - Configuration: CHO–(H–OH)–(H–OH)–(OH–H)–CH₂OH 4. **D-Lyxose** - Configuration: CHO–(OH–H)–(H–OH)–(H–OH)–CH₂OH **Names of Corresponding L Structures:** - **L-Ribose** - **L-Arabinose** - **L-Xylose** - **L-Lyxose** **Graph/Diagram Explanation:** The graphical section displays linear structural formulas of four D-aldopentoses, each consisting of five carbon atoms. They are arranged vertically with: - An aldehyde group (CHO) at the top, - Three hydroxyl groups (OH) each attached to their respective carbon atoms, which are shown in different stereochemical configurations, - A terminal CH₂OH group at the bottom. The configurations indicate the orientation of the hydroxyl groups which are crucial in determining optical activity upon reduction.
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