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Formation of soluble silver-ammonium complex, in an AgCl solution, occurs in a 3-step process: AgCI(s) Ag* (aq) + CH(aq) Ag*(aq) + NH,(aq) 2 AGNH, (aq) K, AGNH, (aq) + NH,(aq) Ag(NH,)2"(aq) K2 where K, is the solubility product for AgCl and K, & K2 are the equilibrium constants for the complex formation. The over-all formation constant (K,) for the Ag(NH;), complex is equal to K, x K2.

Formation of soluble silver-ammonium complex, in an AgCl solution, occurs in a 3-step process: AgCI(s) Ag* (aq) + CH(aq) Ag*(aq) + NH,(aq) 2 AGNH, (aq) K, AGNH, (aq) + NH,(aq) Ag(NH,)2"(aq) K2 where K, is the solubility product for AgCl and K, & K2 are the equilibrium constants for the complex formation. The over-all formation constant (K,) for the Ag(NH;), complex is equal to K, x K2.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Based on the chemical equation provided, which of the following is equivalent to K1? 

a. [Ag+] [Cl-]

b. [AgNH3] / {[Ag+][NH3]}

c. [Ag(NH3)2+] / {[Ag(NH3)+][NH3]}

d. [Ag(NH3)2+] / {[Ag+][NH3+]2}

Formation of soluble silver-ammonium complex, in an AgCl solution, occurs in a 3-step process: AgCI(s)= Ag* (aq) + CH(aq) Ag*(aq) + NH,(aq) AGNH, (aq) AGNH, (aq) + NH,(aq) = Ag(NH3)2'(aq) K2 K, where K, is the solubility product for AgCl and K, & K2 are the equilibrium constants for the complex formation. The over-all formation constant (K,) for the Ag(NH,)," complex is equal to K, x K2.
Transcribed Image Text:Formation of soluble silver-ammonium complex, in an AgCl solution, occurs in a 3-step process: AgCI(s)= Ag* (aq) + CH(aq) Ag*(aq) + NH,(aq) AGNH, (aq) AGNH, (aq) + NH,(aq) = Ag(NH3)2'(aq) K2 K, where K, is the solubility product for AgCl and K, & K2 are the equilibrium constants for the complex formation. The over-all formation constant (K,) for the Ag(NH,)," complex is equal to K, x K2.
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