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For vibrational states, the Boltzmann equation can be written as = exp(-AE/kT) where N, and N, are the populations of the lower and higher energy states, respectively, AE is the energy difference between the states, k is Boltzmann's constant, and Tis the temperature in kelvins. For temperatures of 20°C and 40°C, cakulate the ratios of the intensities of the anti-Stokes and Stokes lines for CCI, at (a) 218 cm-, (b) 459 cm", (c) 790 cm-!. For each temperature and Raman shift, calculate how much more intense the Stokes line is compared to the anti-Stokes line.

For vibrational states, the Boltzmann equation can be written as = exp(-AE/kT) where N, and N, are the populations of the lower and higher energy states, respectively, AE is the energy difference between the states, k is Boltzmann's constant, and Tis the temperature in kelvins. For temperatures of 20°C and 40°C, cakulate the ratios of the intensities of the anti-Stokes and Stokes lines for CCI, at (a) 218 cm-, (b) 459 cm", (c) 790 cm-!. For each temperature and Raman shift, calculate how much more intense the Stokes line is compared to the anti-Stokes line.

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For vibrational states, the Boltzmann equation can be written as = exp(-AE/kT) where N, and N, are the populations of the lower and higher energy states, respectively, AE is the energy difference between the states, k is Boltzmann's constant, and Tis the temperature in kelvins. For temperatures of 20°C and 40°C, cakulate the ratios of the intensities of the anti-Stokes and Stokes lines for CCI, at (a) 218 cm-, (b) 459 cm", (c) 790 cm-!. For each temperature and Raman shift, calculate how much more intense the Stokes line is compared to the anti-Stokes line.
Transcribed Image Text:For vibrational states, the Boltzmann equation can be written as = exp(-AE/kT) where N, and N, are the populations of the lower and higher energy states, respectively, AE is the energy difference between the states, k is Boltzmann's constant, and Tis the temperature in kelvins. For temperatures of 20°C and 40°C, cakulate the ratios of the intensities of the anti-Stokes and Stokes lines for CCI, at (a) 218 cm-, (b) 459 cm", (c) 790 cm-!. For each temperature and Raman shift, calculate how much more intense the Stokes line is compared to the anti-Stokes line.
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