For the reactions I+I+ M → I2 + M Br + Br + M → Br2 + M the rate laws are [I]P dt k[I}[M] d[Br] ks:[Br]*[M] dt The ratio k/kBr at 500°C is 3.0 when M is an Ar molecule. Initially, [I], = 2[Br]o, while [M] is the same for both reac- tions and is much greater than [I]o. Čalculate the ratio of the time required for [I] to decrease to half its initial value to the same time for [Br] at 500°C.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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For the reactions
I+I+ M → I2 + M
Br + Br + M → Br2 + M
the rate laws are
[I]P
dt
k[I}[M]
d[Br]
ks:[Br]*[M]
dt
The ratio k/kBr at 500°C is 3.0 when M is an Ar molecule.
Initially, [I], = 2[Br]o, while [M] is the same for both reac-
tions and is much greater than [I]o. Čalculate the ratio of
Transcribed Image Text:For the reactions I+I+ M → I2 + M Br + Br + M → Br2 + M the rate laws are [I]P dt k[I}[M] d[Br] ks:[Br]*[M] dt The ratio k/kBr at 500°C is 3.0 when M is an Ar molecule. Initially, [I], = 2[Br]o, while [M] is the same for both reac- tions and is much greater than [I]o. Čalculate the ratio of
the time required for [I] to decrease to half its initial value
to the same time for [Br] at 500°C.
Transcribed Image Text:the time required for [I] to decrease to half its initial value to the same time for [Br] at 500°C.
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