For the reaction NO₂(g) + SO₂(g) → NO(g) + SO3(g), AH° = -41.8 kJ. How will the equilibrium concentration of NO be affected if: NO₂ is removed from the container. O Concentration stays the same. O Concentration decreases. O Concentration increases. SO3 is added to the container. Concentration increases. O Concentration stays the same. O Concentration decreases. The temperature of the reaction mixture is raised. O Concentration increases. Concentration stays the same. O Concentration decreases. SO₂ is removed from the container. O Concentration stays the same. O Concentration decreased. O Concentration increased. The pressure of the gas mixture is raised by compressing the volume to 3.00 L. O Concentration decreases. O Concentration stays the same. O Concentration increases.

For the reaction NO₂(g) + SO₂(g) → NO(g) + SO3(g), AH° = -41.8 kJ. How will the equilibrium concentration of NO be affected if: NO₂ is removed from the container. O Concentration stays the same. O Concentration decreases. O Concentration increases. SO3 is added to the container. Concentration increases. O Concentration stays the same. O Concentration decreases. The temperature of the reaction mixture is raised. O Concentration increases. Concentration stays the same. O Concentration decreases. SO₂ is removed from the container. O Concentration stays the same. O Concentration decreased. O Concentration increased. The pressure of the gas mixture is raised by compressing the volume to 3.00 L. O Concentration decreases. O Concentration stays the same. O Concentration increases.

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter12: Chemical Equilibrium

Section: Chapter Questions

Problem 12.103PAE: 12.103 Methanol, CH3OH, can be produced by the reaction of CO with H2, with the liberation of heat....

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Kp for the following reaction is 0.16 at 25 C: 2 NOBr(g) 2 NO(g) + Br2(g) The enthalpy change for the reaction at standard conditions is + 16.3 kJ/mol-rxn. Predict the effect of the following changes on the position of the equilibrium; that is, state which way the equilibrium will shift (left, right, or no change) when each of the following changes is made. (a) adding more Br2(g) (b) removing some NOBr(g) (c) decreasing the temperature (d) increasing the container volume
12.108 A nuclear engineer is considering the effect of discharging waste heat from a power plant into a lake and estimates that this may warm the water locally to 25 °C. One question to be considered is the effect of this temperature change on the uptake of CO2 by the water. The equilibrium constant for the reaction CO2+H2OH2CO3 ; is K=1.7103 at 25 °C. Because bonds form, the reaction is exothermic. (a) Will this reaction progress further toward products at higher temperatures near the water discharge with its warmer water than it would in the cooler lake water? Explain your reasoning. (b) Carbonic acid has a Kaof 2.5104 at 25 °C. What is the equilibrium constant for the CO2+2H2OHCO3+H3O+? (c) What additional factor should the engineer be considering about CO2 gas, probably before considering this reaction chemistry?
Consider the system 4 NH3(g) + 3 O2(g) ⇌ 2 N2(g) + 6 H20(ℓ) ΔrH° = −1530.4 kJ/mol How will the amount of ammonia at equilibrium be affected by removing O2(g) without changing the total gas volume? adding N2(g) without changing the total gas volume? adding water without changing the total gas volume? expanding the container? increasing the temperature? Which of these changes (i to v) increases the value of K? Which decreases it?
Organ pipes in unheated churches develop tin disease, in which white tin is converted to gray tin. Given white Sm: H f =0.00 kJ/mol; S =51.55 J/mol K gray Sn: H f =2.09 kJ/mol; S =44.14 J/mol K calculate the equilibrium temperature for the transition.
Predict whether each of the following processes results in an increase in entropy in the system. (Define reactants and products as the system.) (a) Water vapor condenses to liquid water at 90 C and 1 atm pressure. (b) The exothermic reaction of Na(s) and Cl2(g) forms NaCl(s). (c) The endothermic reaction of H2 and I2 produces an equilibrium mixture of H2(g), I2(g), and HI(g). (d) Solid NaCl dissolves in water forming a saturated solution.
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12.101 An engineer working on a design to extract petroleum from a deep thermal reservoir wishes to capture toxic hydrogen sulfide gases present by reaction with aqueous iron(II) nitrate to form solid iron(II) sulfide. (a) Write the chemical equation for this process, assuming that it reaches equilibrium. (b) What is the equilibrium constant expression for this system? (c) How can the process be manipulated so that it does not reach equilibrium, allowing the continuous removal of hydrogen sulfide?
Consider the following relationships: G = 1, H = TS, Q = 1. G = G, K = 1 Which of these relationships is(are) always true for a reaction at equilibrium?
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12.103 Methanol, CH3OH, can be produced by the reaction of CO with H2, with the liberation of heat. All species in the reaction are gaseous. What effect will each of the following have on the equilibrium concentration of CO? (a) Pressure is increased, (b) volume of the reaction container is decreased, (c) heat is added, (d) the concentration of CO is increased, (e) some methanol is removed from the container, and (f) H2 is added.
In Section 13.1 of your text, it is mentioned that equilibrium is reached in a closed system. What is meant by the term closed system. and why is it necessary to have a closed system in order for a system to reach equilibrium? Explain why equilibrium is not reached in an open system.