For the questions of Exp 20 Electrochemistry,Part B: EMF of Galvanic CellTable 2: Electromotive force of the galvanic cell found throughthe mixtures of different solutions in part B of the experimentExperiment Solution AElectrode A Solution BElectrode B#4Sn2+SnCu2+Cu#7Zn2+Zn0.1 M KCIAg WireAnswer the following question(s).d) Calculate E cell for Experiment #7.

To calculate the Ecellfor Experiment #7 involving a Zn electrode and an Ag wire in the presence of…

Answered: For the questions of Exp 20…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Draw the galvanic cell from the following half-reactions (use KCl as salt bridge) Al3 + aq + 3rd → Als Ni2 + aq + 2é → Ni (s) Indicates the anode and cathode Indicates where oxidation and reduction occur Indicates the direction of movement of electrons. Indicates the direction of movement of the ions. Write the balanced ionic equation of this equation
13. Write the oxidation half reaction, the reduction half reaction, and the overall cell reaction for the following galvanic cell. Identify the anode and the cathode and state why you labeled the metals that way. (4) Zn (s) | Zn²+ (aq) || Cu²+ (aq) | Cu (s)
Consider the galvanic cell based on the following half-reactions. Ag+ + e Ni²+ + 2e →→ Ni (a) Determine the overall cell reaction and calculate Omit states-of-matter from your answer.) chemPad XX→ (c) 8 cell → Ag 8⁰ = +0.80 V 8° -0.23 V Calculate 8 Help Greek º (b) Calculate AGº (in kJ) and K for the cell reaction at 25°C. AGO kJ K (in V). (Use the lowest possible whole number coefficients. cell (in V) at 25°C when [Ag+] = 1.0x10-4 M and [Ni²+] = 1.0×10-² M. cell V
Suppose the left half cell of a galvanic cell apparatus is filled with a 5.00 M solution of A certain metal M forms a soluble sulfate salt M₂ M₂(SO4)3 and the right half cell with a 2.50 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. 0 left right × S
3. Given that the whole standard potential of a Zn-Mg cell is +1.61 V and the standard reduction potential of Zn²+ → Zn is -0.76 V, what is the standard reduction potential of Mg2+→ Mg? -
A galvanic cell was formed using Avium and Beanium:[hypothetical elements] Reduction Potentials: Av3+(aq) + 3e- → Av(s) Eo = -0.48 V Bn4+(aq) + 4e- → Bn(s) Eo = +0.15 V a) Write a net ionic equation for this reaction. b) Write the cell notation for this cell. c) Which is the oxidizing agent? Explain how you know.
A table of standard electrode potentials is necessary for many of the following question(s). Consider the following reaction: If a galvanic cell utilizes this reaction and the initial concentrations are [Hg 2 2+] = 0.10 M, [Sn 2+] = 0.30 M, and [Sn 4+] = 0.20 M, what will be E cell under these conditions? 2+ (aq) + Sn2+ (aq) → Sn4+ (aq) + 2Hg(s) Hg2 a. 0.68 V O b. 0.66 V O c. 0.61 V O d. 0.74 V O e. 0.57 V
A voltaic cell operating under standard conditions (1.0 M ion concentrations) utilizes the following reaction: Cr(s) + 3 Ag*(aq) → Cr³*(aq) + 3 Ag(s) Which of the multiple choices correctly describes how the cell emf changes when a change is made to the cell? Ca) Adding water to the anode compartment makes the cell emf less positive. C b) Increasing the size of the silver electrode makes the cell emf stay the same. C C) Adding a solution of 1.0 M AGNO, to the cathode compartment makes the cell emf more negative. C d) Adding Na,s to the anode compartment to precipitate chromium sulfide makes the cell emf less positive. Ce) Adding a solution of 5 M Ag* to the cathode compartment makes the cell emf stay the same.
MnO4– + Sn ----> MnO2 + Sn2+ A) Identify the half-reaction that occurs at the cathode. B) Identify the oxidizing agent and anode. C) standard cell potential? D) What will be the potential of a cell constructed using 57.0 g MnO2, 1.57 M MnO4–, 14.8 g Pt, 12.5 g Sn and 0.87 M Sn2+ at pH 2.5?
3. The oxidation of methanol, as described by the equation below, has a AG value of -937.9 kJ/mol. What is the standard cell potential for a methanol fuel cell? 2CH3OH +30₂ → 2CO₂ + 4H₂O
A voltaic cell is constructed with two silver–silver chloride electrodes, each of which is based on the following half-reaction: AgCl1s2 + e- ¡ Ag1s2 + Cl -1aq2 The two half-cells have 3Cl -4 = 0.0150 M and 3Cl -4= 2.55 M, respectively. What is the standard emf of the cell?
Calculate Ecell (volts) for the galvanic cell containing the reaction shown below where the concentration of the ion at the anode is 0.400 M and the concentration of the ion at the cathode is 1.86 M.

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