For the complexes given below, answer the following (in all cases, fully justify your answer): 1. Write the systematic name or formula (as the case may be) and draw the complex. ii. Mention whether or not it is a chelate. If there are different isomeric forms, draw them all and clearly indicate the type of isomerism. iii. Fill in the corresponding crystal field doubling diagram and predict its magnetic behavior (you must indicate the number of unpaired e's and it will be high or low spin, when this makes sense). a) (PH4) 2 [FeCl2 (NCS) 4] b) [Co (en) 2CN] 3 (PO4) 2 c) Tetraaquodichlorochrome (III) chloride dihydrate

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For the complexes given below, answer the following (in all cases, fully justify your answer):

1. Write the systematic name or formula (as the case may be) and draw the complex.

ii. Mention whether or not it is a chelate. If there are different isomeric forms, draw them all and clearly indicate the type of isomerism.

iii. Fill in the corresponding crystal field doubling diagram and predict its magnetic behavior (you must indicate the number of unpaired e's and it will be high or low spin, when this makes sense).

a) (PH4) 2 [FeCl2 (NCS) 4]

b) [Co (en) 2CN] 3 (PO4) 2

c) Tetraaquodichlorochrome (III) chloride dihydrate

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