For the batch reaction as specified above, carry out a degree-of-freedom analysis. How many elemental balances may be written? How many degrees of freedom remain? 51

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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At low to moderate pressures, the equilibrium state of the water-gas shift reaction:

\[ \text{CO} + \text{H}_2\text{O} \rightleftarrows \text{CO}_2 + \text{H}_2} \]

is approximately described by the relation:

\[
\frac{y_{\text{CO}_2} \cdot y_{\text{H}_2}}{y_{\text{CO}} \cdot y_{\text{H}_2\text{O}}} = K_{\text{eq}}(T) = 0.0247 \exp\left[\frac{4020}{T (\text{K})}\right]
\]

where \( T \) is the reactor temperature, \( K_{\text{eq}} \) is the reaction equilibrium constant, and \( y_i \) is the mole fraction of species \( i \) in the reactor contents at equilibrium.

The feed to a batch shift reactor contains 30.0 mol% CO, 10.0 mol% CO₂, 40.0 mol% H₂O, and the balance is an inert gas. The reactor is maintained at \( T = 1223 \text{ K} \).
Transcribed Image Text:At low to moderate pressures, the equilibrium state of the water-gas shift reaction: \[ \text{CO} + \text{H}_2\text{O} \rightleftarrows \text{CO}_2 + \text{H}_2} \] is approximately described by the relation: \[ \frac{y_{\text{CO}_2} \cdot y_{\text{H}_2}}{y_{\text{CO}} \cdot y_{\text{H}_2\text{O}}} = K_{\text{eq}}(T) = 0.0247 \exp\left[\frac{4020}{T (\text{K})}\right] \] where \( T \) is the reactor temperature, \( K_{\text{eq}} \) is the reaction equilibrium constant, and \( y_i \) is the mole fraction of species \( i \) in the reactor contents at equilibrium. The feed to a batch shift reactor contains 30.0 mol% CO, 10.0 mol% CO₂, 40.0 mol% H₂O, and the balance is an inert gas. The reactor is maintained at \( T = 1223 \text{ K} \).
**Degrees of Freedom**

For the batch reaction as specified above, carry out a degree-of-freedom analysis.

- **How many elemental balances may be written?**  
  [Input box]

- **How many degrees of freedom remain?**  
  [Input box]

Additional Resources:
- **eTextbook and Media**
- **Hint**

Note: There are no graphs or diagrams in this image.
Transcribed Image Text:**Degrees of Freedom** For the batch reaction as specified above, carry out a degree-of-freedom analysis. - **How many elemental balances may be written?** [Input box] - **How many degrees of freedom remain?** [Input box] Additional Resources: - **eTextbook and Media** - **Hint** Note: There are no graphs or diagrams in this image.
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Step 1: Given data:


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space space space space space space space space space space equals space 15 space m o l percent sign thin space i n e r t

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