For the batch reaction as specified above, carry out a degree-of-freedom analysis. How many elemental balances may be written? How many degrees of freedom remain? 51
For the batch reaction as specified above, carry out a degree-of-freedom analysis. How many elemental balances may be written? How many degrees of freedom remain? 51
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
Help with the following question.
![At low to moderate pressures, the equilibrium state of the water-gas shift reaction:
\[ \text{CO} + \text{H}_2\text{O} \rightleftarrows \text{CO}_2 + \text{H}_2} \]
is approximately described by the relation:
\[
\frac{y_{\text{CO}_2} \cdot y_{\text{H}_2}}{y_{\text{CO}} \cdot y_{\text{H}_2\text{O}}} = K_{\text{eq}}(T) = 0.0247 \exp\left[\frac{4020}{T (\text{K})}\right]
\]
where \( T \) is the reactor temperature, \( K_{\text{eq}} \) is the reaction equilibrium constant, and \( y_i \) is the mole fraction of species \( i \) in the reactor contents at equilibrium.
The feed to a batch shift reactor contains 30.0 mol% CO, 10.0 mol% CO₂, 40.0 mol% H₂O, and the balance is an inert gas. The reactor is maintained at \( T = 1223 \text{ K} \).](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcef3f1b2-56cd-4f45-949e-fc7a38ef994c%2Fdcb7cc32-09a7-4728-8195-1cd099f90c45%2Fhui83eg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:At low to moderate pressures, the equilibrium state of the water-gas shift reaction:
\[ \text{CO} + \text{H}_2\text{O} \rightleftarrows \text{CO}_2 + \text{H}_2} \]
is approximately described by the relation:
\[
\frac{y_{\text{CO}_2} \cdot y_{\text{H}_2}}{y_{\text{CO}} \cdot y_{\text{H}_2\text{O}}} = K_{\text{eq}}(T) = 0.0247 \exp\left[\frac{4020}{T (\text{K})}\right]
\]
where \( T \) is the reactor temperature, \( K_{\text{eq}} \) is the reaction equilibrium constant, and \( y_i \) is the mole fraction of species \( i \) in the reactor contents at equilibrium.
The feed to a batch shift reactor contains 30.0 mol% CO, 10.0 mol% CO₂, 40.0 mol% H₂O, and the balance is an inert gas. The reactor is maintained at \( T = 1223 \text{ K} \).
![**Degrees of Freedom**
For the batch reaction as specified above, carry out a degree-of-freedom analysis.
- **How many elemental balances may be written?**
[Input box]
- **How many degrees of freedom remain?**
[Input box]
Additional Resources:
- **eTextbook and Media**
- **Hint**
Note: There are no graphs or diagrams in this image.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcef3f1b2-56cd-4f45-949e-fc7a38ef994c%2Fdcb7cc32-09a7-4728-8195-1cd099f90c45%2Fkdjae3n_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Degrees of Freedom**
For the batch reaction as specified above, carry out a degree-of-freedom analysis.
- **How many elemental balances may be written?**
[Input box]
- **How many degrees of freedom remain?**
[Input box]
Additional Resources:
- **eTextbook and Media**
- **Hint**
Note: There are no graphs or diagrams in this image.
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