For Styrene gas, calculate the following: ) Second virial coefficient (B). (i) Fugacity coefficient, f using B. (iii) Fugacity, f. (iv)Volume, V. Given data: B° = 0.083 - (0.422/T,6) BPe %3D B° + wB'; T, =;P, %3D %3D %3D RTC Pe B = 0.139 - (0.172/T,²) %3D BP Z = 1+ RT 1+ B T, %3D Ø = fe = exp (B° + wB %3! %3D R= 8.314 J/mol.K 1 bar = 1x 10 N/m2
For Styrene gas, calculate the following: ) Second virial coefficient (B). (i) Fugacity coefficient, f using B. (iii) Fugacity, f. (iv)Volume, V. Given data: B° = 0.083 - (0.422/T,6) BPe %3D B° + wB'; T, =;P, %3D %3D %3D RTC Pe B = 0.139 - (0.172/T,²) %3D BP Z = 1+ RT 1+ B T, %3D Ø = fe = exp (B° + wB %3! %3D R= 8.314 J/mol.K 1 bar = 1x 10 N/m2
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:For Styrene gas, calculate the following:
) Second virial coefficient (B).
(ii) Fugacity coefficient, f, using B.
(iii) Fugacity, f.
(iv)Volume, V.
Given data:
B° = 0.083 - (0.422/T,6)
= B° + wB'; T, = P, =
%3D
%3D
RT
Pc
B = 0.139 - (0.172/T*²)
%3D
P,
ВР
Z = 1+
=1+ B
RT
f
Ø = fe = =
= exp
(B° + wB'
%3D
R= 8.314 J/mol.K
1 bar = 1x 10S N/m2
A-
I
!
Transcribed Image Text:Styrene gas is stored in a petrochemical plant at 590 K and 20 bar. The properties of the gas
are given below in Table Q1.
Table Q1: Properties of Pure species
Ve
cm3 mol- T/K
Molar
mass
TJK
P/bar
Ze
70.134
0.196
511.8
45.02
0.273
258.
322.4
Cyclopentane
Cyclohexane
Methylcyclopentane
Methylcyclohexane
Ethylene
Propylene
1-Butene
84.161
0.210
553.6
40.73
0.273
308.
353.9
37.85
0.272
319.
345.0
532.8
572.2
282.3
84.161
0.230
98.188
0.235
34.71
0.269
368.
374.1
28.054
0.087
50.40
0.281
131.
169.4
42.081
0.140
365.6
46.65
0.289
188.4
225.5
56.108
0.191
420.0
40.43
0.277
239.3
266.9
cis-2-Butene
56.108
0.205
435.6
42.43
0.273
233.8
276.9
237.7
354.
56.108
0.218
428.6
41.00 0.275
274.0
trans-2-Butene
1-Hexene
84.161
0.280
504.0
31.40
0.265
336.3
0.275
0.267
266.3
268.7
417.9
40.00
238.9
56.108
54.092
0.194
Isobutylene
1,3-Butadiene
0.190
425.2
42.77
220.4
82.145
0.212
560.4
43.50
0.272
291.
356.1
Cyclohexene
Acetylene
26.038
0.187
308.3
61.39
0.271
113.
189.4
78.114
0.210
562.2
48.98
0.271
259.
353.2
Benzene
Toluene
92.141
0.262
591.8
41.06 0.264
316.
383.8
106.167
0.303
617.2
36.06
0.263
374.
409.4
Ethylbenzene
Cumene
120.194
0.326
631.1
32.09
0.261
427.
425.6
106.167
0.310
630.3
37.34 0.263
369.
417.6
o-Xylene
m-Xylene
p-Xylene
Styrene
376.
379.
106.167
0.326
617.1
35.36
0.259
412.3
106.167
0.322
616.2
35.11
0.260
411.5
104.152
0.297
636.0
38.40
0.256
352.
418.3
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