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For Propylene gas, calculate the following: () Second virial coefficient (B). (ii) Fugacity coefficient, f. using B (iii) Fugacity, f (iv) Volume, v

For Propylene gas, calculate the following: () Second virial coefficient (B). (ii) Fugacity coefficient, f. using B (iii) Fugacity, f (iv) Volume, v

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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For Propylene gas, calculate the following: () Second virial coefficient (B). (ii) Fugacity coefficient, f. using B (iii) Fugacity, f (iv) Volume, v
Given data B° = 0.083 – (0.422/T,6) BPc - B0 + wB; T, RTC Tc Pc B' = 0.139 – (0.172/T,* 2) BP =1+ RT P, Z = 1+ BT f Ø = fe exp P. (B° + wB R= 8.314 J/mol K 1 bar = 1x 10$N/m2 P.
Transcribed Image Text:Given data B° = 0.083 – (0.422/T,6) BPc - B0 + wB; T, RTC Tc Pc B' = 0.139 – (0.172/T,* 2) BP =1+ RT P, Z = 1+ BT f Ø = fe exp P. (B° + wB R= 8.314 J/mol K 1 bar = 1x 10$N/m2 P.
Propylene gas is stored in a petrochemical plant at 330 K and 16 bar. The properties of the gas are given below in Table Q1. Fir Table Q1: Properties of Pure species 00 Ti Molar TJK P/bar cm3-mol-! T/K mass Cyclopentane Cyclohexane Methylcyclopentane Methylcyclohexane Ethylene Propylene 1-Butene 70.134 0.196 511.8 45.02 0.273 258. 322.4 84.161 0.210 553.6 40.73 0.273 308. 353.9 84.161 0.230 532.8 37.85 0.272 319. 345.0 98.188 0.235 572.2 34.71 0.269 368. 374.1 28.054 0.087 282.3 50.40 0.281 131. 169.4 42.081 0.140 365.6 46.65 0.289 188.4 225.5 56.108 0.191 420.0 40.43 0.277 239.3 266.9 cis-2-Butene trans-2-Butene 1-Hexene 56.108 0.205 435.6 42.43 0.273 3.8 276.9 56.108 0.218 428.6 41.00 0.275 237.7 274.0 84.161 0.280 504.0 31.40 0,265 354 336.3 Isobutylene 1.3-Butadiene Cyclohexene Acetylene Benzene 56.108 0.194 417.9 40.00 0.275 238.9 266.3 54.092 0.190 425.2 42.77 (0.267 220.4 268.7 82.145 0.212 560.4 (0.272 0.271 0.271 0.264 0.263 0.261 0.263 43.50 291. 356.1 26.038 78.114 92.141 0.187 308.3 61.39 113. 189.4 0.210 562.2 48.98 259. 353.2 Toluene 0.262 591.8 41,06 316. 374. 427 569. 383.8 409.4 425 6 417.6 Ethylbenzene Cumene 106.167 36.06 32.09 37.34 0.303 617.2 120.194 0.326 631.1 o-Xylene m-Xylene p-Xylene Styrene 106.167 0.310 630.3 106.167 0.326 617.1 35 36 35.11 0.260 38.40 106.167 0.322 616.2 636.0 104.152 0.297
Transcribed Image Text:Propylene gas is stored in a petrochemical plant at 330 K and 16 bar. The properties of the gas are given below in Table Q1. Fir Table Q1: Properties of Pure species 00 Ti Molar TJK P/bar cm3-mol-! T/K mass Cyclopentane Cyclohexane Methylcyclopentane Methylcyclohexane Ethylene Propylene 1-Butene 70.134 0.196 511.8 45.02 0.273 258. 322.4 84.161 0.210 553.6 40.73 0.273 308. 353.9 84.161 0.230 532.8 37.85 0.272 319. 345.0 98.188 0.235 572.2 34.71 0.269 368. 374.1 28.054 0.087 282.3 50.40 0.281 131. 169.4 42.081 0.140 365.6 46.65 0.289 188.4 225.5 56.108 0.191 420.0 40.43 0.277 239.3 266.9 cis-2-Butene trans-2-Butene 1-Hexene 56.108 0.205 435.6 42.43 0.273 3.8 276.9 56.108 0.218 428.6 41.00 0.275 237.7 274.0 84.161 0.280 504.0 31.40 0,265 354 336.3 Isobutylene 1.3-Butadiene Cyclohexene Acetylene Benzene 56.108 0.194 417.9 40.00 0.275 238.9 266.3 54.092 0.190 425.2 42.77 (0.267 220.4 268.7 82.145 0.212 560.4 (0.272 0.271 0.271 0.264 0.263 0.261 0.263 43.50 291. 356.1 26.038 78.114 92.141 0.187 308.3 61.39 113. 189.4 0.210 562.2 48.98 259. 353.2 Toluene 0.262 591.8 41,06 316. 374. 427 569. 383.8 409.4 425 6 417.6 Ethylbenzene Cumene 106.167 36.06 32.09 37.34 0.303 617.2 120.194 0.326 631.1 o-Xylene m-Xylene p-Xylene Styrene 106.167 0.310 630.3 106.167 0.326 617.1 35 36 35.11 0.260 38.40 106.167 0.322 616.2 636.0 104.152 0.297
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