Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Solubility Ranking of Organic Molecules
#### Task:
For each of the two horizontal series below, rank each molecule from highest (1) to lowest solubility in water.
### First Series:
#### Molecules and Molecular Weights:
1. **Molecule 1:**
- Structure:
- Ethanol with one additional carbon (Butanol).
- Molecular Formula: C3H7OH
- Molecular Weight: 74.12 g/mol
2. **Molecule 2:**
- Structure:
- Ethanol with two additional carbons (Pentanol).
- Molecular Formula: C4H9OH
- Molecular Weight: 88.15 g/mol
3. **Molecule 3:**
- Structure:
- Ethanol with three additional carbons (Hexanol).
- Molecular Formula: C5H11OH
- Molecular Weight: 102.18 g/mol
### Second Series:
#### Molecules and Molecular Weights:
1. **Molecule 1:**
- Structure:
- Propanone (Acetone).
- Molecular Formula: C3H6O
- Molecular Weight: 58.08 g/mol
2. **Molecule 2:**
- Structure:
- Propanol.
- Molecular Formula: C3H8O
- Molecular Weight: 60.10 g/mol
3. **Molecule 3:**
- Structure:
- Ethanoic Acid (Acetic Acid).
- Molecular Formula: C2H4O2
- Molecular Weight: 59.04 g/mol
4. **Molecule 4:**
- Structure:
- Ethyl Methyl Ether.
- Molecular Formula: C3H8O
- Molecular Weight: 60.10 g/mol
---
### Explanation of Solubility:
#### General Principles:
- **Solubility in Water:** In general, solubility of organic molecules in water decreases as the length of the carbon chain increases. This is due to the increased hydrophobic (water-repelling) nature of larger alkyl groups.
- **Functional Groups:** Molecules with polar functional groups (e.g., -OH, =O) are generally more soluble in water compared to nonpolar molecules of similar size.
#### Analysis of the First Series:
-](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F8cd017c2-5594-4f32-998a-c1390ce1b0d0%2F0719e47c-5937-4fb8-9d01-f45f650d4c20%2F68j6mv3.jpeg&w=3840&q=75)
Transcribed Image Text:### Solubility Ranking of Organic Molecules
#### Task:
For each of the two horizontal series below, rank each molecule from highest (1) to lowest solubility in water.
### First Series:
#### Molecules and Molecular Weights:
1. **Molecule 1:**
- Structure:
- Ethanol with one additional carbon (Butanol).
- Molecular Formula: C3H7OH
- Molecular Weight: 74.12 g/mol
2. **Molecule 2:**
- Structure:
- Ethanol with two additional carbons (Pentanol).
- Molecular Formula: C4H9OH
- Molecular Weight: 88.15 g/mol
3. **Molecule 3:**
- Structure:
- Ethanol with three additional carbons (Hexanol).
- Molecular Formula: C5H11OH
- Molecular Weight: 102.18 g/mol
### Second Series:
#### Molecules and Molecular Weights:
1. **Molecule 1:**
- Structure:
- Propanone (Acetone).
- Molecular Formula: C3H6O
- Molecular Weight: 58.08 g/mol
2. **Molecule 2:**
- Structure:
- Propanol.
- Molecular Formula: C3H8O
- Molecular Weight: 60.10 g/mol
3. **Molecule 3:**
- Structure:
- Ethanoic Acid (Acetic Acid).
- Molecular Formula: C2H4O2
- Molecular Weight: 59.04 g/mol
4. **Molecule 4:**
- Structure:
- Ethyl Methyl Ether.
- Molecular Formula: C3H8O
- Molecular Weight: 60.10 g/mol
---
### Explanation of Solubility:
#### General Principles:
- **Solubility in Water:** In general, solubility of organic molecules in water decreases as the length of the carbon chain increases. This is due to the increased hydrophobic (water-repelling) nature of larger alkyl groups.
- **Functional Groups:** Molecules with polar functional groups (e.g., -OH, =O) are generally more soluble in water compared to nonpolar molecules of similar size.
#### Analysis of the First Series:
-
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