Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
For each of the following compounds, give the correct R/S notation for all stereocenters
Expert Solution
Step 1
To determine R/S nomenclature, priorities are given by CIP rule -
1. Higher the atomic number of an atom, higher will be it's priority. For example, F ˃ H (atomic number of F is 9 while atomic number of H is 1)
2. If rule (1) fails, then priorities are given by considering atomic masses. Higher the atomic mass greater will be priority. For example, 3T1˃2D1˃1H1
3. Cis-isomer has greater priority than trans-isomer.
4. R ˃ S
5. Atom ˃ lone pair of electron
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