For both of the following questions, please indicate whether the arrows represent the movement of one electron or a pair of electrons!

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For both of the following questions, please indicate whether the arrows represent the movement of one electron or a pair of electrons!

C=CH
C↔X =
Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II)
sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group
adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial
product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more
stable ketone via tautomerization.
Draw curved arro to show the movement of electrons in this step of the mechanism.
Arrow-pushing Instructions
C=CH
H₂O, H₂SO4
HgSO4
Hg²+
CH3
c=cH
Hg
Transcribed Image Text:C=CH C↔X = Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arro to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions C=CH H₂O, H₂SO4 HgSO4 Hg²+ CH3 c=cH Hg
N
C=CH
Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II)
sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group
adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial
product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more
stable ketone via tautomerization.
Draw curved arrows to show the movement of electrons in this step of the mechanism.
Arrow-pushing Instructions
C↔XT
HO
H₂O, H₂SO4
HgSO4
C=CH₂
CH3
H-OH₂
HO
-CH3
H₂O
Transcribed Image Text:N C=CH Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions C↔XT HO H₂O, H₂SO4 HgSO4 C=CH₂ CH3 H-OH₂ HO -CH3 H₂O
Expert Solution
Step 1

We have given two mechanisms and we have to draw the curved arrows for the steps of the mechanism. Organic compounds are the compounds that contain carbon and hydrogen atoms.

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