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For Acetylene gas, calculate the following: (i) Second virial coefficient (B). (ii) Fugacity coefficient, f, using B. (iii) Fugacity, f. (iv)Volume, V.

For Acetylene gas, calculate the following: (i) Second virial coefficient (B). (ii) Fugacity coefficient, f, using B. (iii) Fugacity, f. (iv)Volume, V.

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Acetylene gas is stored in a petrochemical plant at 298 K and 30 bar. The properties of the gas are given below in Table Q1. Table Q1: Properties of Pure species Molar T/K P /bar Ze cm³-mol-1 T/K mass 511.8 0.273 Cyclopentane Cyclohexane Methylcyclopentane Methylcyclohexane Ethylene Propylene 70.134 0.196 45.02 258. 322.4 84.161 0.210 553.6 40.73 0.273 308. 353.9 84.161 0.230 532.8 37.85 0.272 319. 345.0 98.188 0.235 572.2 34.71 0.269 368. 374.1 28.054 0.087 282.3 50.40 0.281 131. 169.4 42.081 0.140 365.6 46.65 0.289 188.4 225.5 1-Butene 56.108 0.191 420.0 40.43 0.277 239.3 266.9 cis-2-Butene 56.108 0.205 435.6 42.43 0.273 233.8 276.9 trans-2-Butene 56.108 0.218 428.6 41.00 0.275 237.7 274.0 1-Нехene 84.161 0.280 504.0 31.40 0.265 354. 336.3 Isobutylene 1,3-Butadiene Cyclohexene Acetylene 56.108 0.194 417.9 40.00 0.275 238.9 266.3 54.092 0.190 425.2 42.77 0.267 220.4 268.7 82.145 0.212 560.4 43.50 0.272 291. 356.1 26.038 0.187 308.3 61.39 0.271 113. 189.4 Benzene 78.114 0.210 562.2 48.98 0.271 259. 353.2 Toluene 92.141 0.262 591.8 41.06 0.264 316. 383.8 409.4 Ethylbenzene Cumene 106.167 0.303 617.2 36.06 0.263 374. 120.194 0.326 631.1 32.09 0.261 427. 425.6 o-Xylene т-Хylene р-Хylene Styrene 106.167 0.310 630.3 37.34 0.263 369. 417.6 106.167 0.326 617.1 35.36 0.259 376. 412.3 106.167 0.322 616.2 35.11 0.260 379. 411.5 104.152 0.297 636.0 38.40 0.256 352. 418.3
Transcribed Image Text:Acetylene gas is stored in a petrochemical plant at 298 K and 30 bar. The properties of the gas are given below in Table Q1. Table Q1: Properties of Pure species Molar T/K P /bar Ze cm³-mol-1 T/K mass 511.8 0.273 Cyclopentane Cyclohexane Methylcyclopentane Methylcyclohexane Ethylene Propylene 70.134 0.196 45.02 258. 322.4 84.161 0.210 553.6 40.73 0.273 308. 353.9 84.161 0.230 532.8 37.85 0.272 319. 345.0 98.188 0.235 572.2 34.71 0.269 368. 374.1 28.054 0.087 282.3 50.40 0.281 131. 169.4 42.081 0.140 365.6 46.65 0.289 188.4 225.5 1-Butene 56.108 0.191 420.0 40.43 0.277 239.3 266.9 cis-2-Butene 56.108 0.205 435.6 42.43 0.273 233.8 276.9 trans-2-Butene 56.108 0.218 428.6 41.00 0.275 237.7 274.0 1-Нехene 84.161 0.280 504.0 31.40 0.265 354. 336.3 Isobutylene 1,3-Butadiene Cyclohexene Acetylene 56.108 0.194 417.9 40.00 0.275 238.9 266.3 54.092 0.190 425.2 42.77 0.267 220.4 268.7 82.145 0.212 560.4 43.50 0.272 291. 356.1 26.038 0.187 308.3 61.39 0.271 113. 189.4 Benzene 78.114 0.210 562.2 48.98 0.271 259. 353.2 Toluene 92.141 0.262 591.8 41.06 0.264 316. 383.8 409.4 Ethylbenzene Cumene 106.167 0.303 617.2 36.06 0.263 374. 120.194 0.326 631.1 32.09 0.261 427. 425.6 o-Xylene т-Хylene р-Хylene Styrene 106.167 0.310 630.3 37.34 0.263 369. 417.6 106.167 0.326 617.1 35.36 0.259 376. 412.3 106.167 0.322 616.2 35.11 0.260 379. 411.5 104.152 0.297 636.0 38.40 0.256 352. 418.3
For Acetylene gas, calculate the following: (i) Second virial coefficient (B). (ii) Fugacity coefficient, f, using B. (iii) Fugacity, f. (iv)Volume, V. Given data: BPc T B° = 0.083 – (0.422/T,16) B° + wB'; T, Tc %3D %3D RTc Pc B' = 0.139 – (0.172/T,*.2) ВР = 1+ B RT P, T, Z = 1+ f = fe # (B° + wB+) exp R = 8.314 J/mol.K 1 bar = 1x 105 N/m2
Transcribed Image Text:For Acetylene gas, calculate the following: (i) Second virial coefficient (B). (ii) Fugacity coefficient, f, using B. (iii) Fugacity, f. (iv)Volume, V. Given data: BPc T B° = 0.083 – (0.422/T,16) B° + wB'; T, Tc %3D %3D RTc Pc B' = 0.139 – (0.172/T,*.2) ВР = 1+ B RT P, T, Z = 1+ f = fe # (B° + wB+) exp R = 8.314 J/mol.K 1 bar = 1x 105 N/m2
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