For a solution in which u = 8.0 x 10, calculate K', for s. Pbl,. The thermodynamic constant of the solubility -9 constant of Pbl, is 7.9 x 10. Use the linear interpolation of experimental data below. TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated lonic Strength lon 0.001 0.005 0.01 0.05 0.1 H,O L. CH,CO0 Na". 10,, HSO,. HCO,. H,PO,. HASO, OAC OH,F. SCN, HS", CIO,. CIO,. HrO,. 10,, MnO, K*. Cr, Br,I, CN", NO,, NO,. HCOO- Rb", C. TI'. Ag". NH," Mg*, Be G.. Za". Sa". Ma". Fe", Ni", Co". Phchalate St, Ba", Cd", Hg", s P, Co,. So,.CO He", so,", S,0,", Cr", HPO, AP. Fe. C, La, Ce PO,. Fe(CN), Th, Z, Ce, Sn* Fe(CN), 0.85 0.83 0.9 0.967 0.934 0.913 0.83 0.6 0.966 0.930 0.907 0.80 0.4-0.45 0.965 0.927 0.902 0.82 0.77 0.926 0.925 0.76 0.75 0.35 0.965 0.900 0.81 0.899 0.897 0.3 0.965 0.81 0.25 0.965 0.925 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.6 0.870 0.748 0.676 0.48 0.40 0.743 0.741 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.665 0.45 0.36 0.40 0.867 0.738 0.661 0.44 0.35 0.9 0.737 0.540 0.443 0.24 0.18 0.4 0.726 0.505 0.394 0.16 0.095 0.063 1.1 0.587 0.569 0.348 0.252 0.10 0.5 0.305 0.200 0.047 0.020 Source Reprinted tadapted) with permision from J. Kielland. I Am. Chem. Sac, 1937, 59, 1675, DOI 10.1021/ja01288a2. Cepyright 1937 Ametican Chemical Society
For a solution in which u = 8.0 x 10, calculate K', for s. Pbl,. The thermodynamic constant of the solubility -9 constant of Pbl, is 7.9 x 10. Use the linear interpolation of experimental data below. TABLE 10-2 Activity Coefficients for Ions at 25°C Activity Coefficient at Indicated lonic Strength lon 0.001 0.005 0.01 0.05 0.1 H,O L. CH,CO0 Na". 10,, HSO,. HCO,. H,PO,. HASO, OAC OH,F. SCN, HS", CIO,. CIO,. HrO,. 10,, MnO, K*. Cr, Br,I, CN", NO,, NO,. HCOO- Rb", C. TI'. Ag". NH," Mg*, Be G.. Za". Sa". Ma". Fe", Ni", Co". Phchalate St, Ba", Cd", Hg", s P, Co,. So,.CO He", so,", S,0,", Cr", HPO, AP. Fe. C, La, Ce PO,. Fe(CN), Th, Z, Ce, Sn* Fe(CN), 0.85 0.83 0.9 0.967 0.934 0.913 0.83 0.6 0.966 0.930 0.907 0.80 0.4-0.45 0.965 0.927 0.902 0.82 0.77 0.926 0.925 0.76 0.75 0.35 0.965 0.900 0.81 0.899 0.897 0.3 0.965 0.81 0.25 0.965 0.925 0.80 0.75 0.8 0.872 0.756 0.690 0.52 0.44 0.6 0.870 0.748 0.676 0.48 0.40 0.743 0.741 0.5 0.869 0.668 0.46 0.38 0.45 0.868 0.665 0.45 0.36 0.40 0.867 0.738 0.661 0.44 0.35 0.9 0.737 0.540 0.443 0.24 0.18 0.4 0.726 0.505 0.394 0.16 0.095 0.063 1.1 0.587 0.569 0.348 0.252 0.10 0.5 0.305 0.200 0.047 0.020 Source Reprinted tadapted) with permision from J. Kielland. I Am. Chem. Sac, 1937, 59, 1675, DOI 10.1021/ja01288a2. Cepyright 1937 Ametican Chemical Society
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
100%
Transcribed Image Text:-2
For a solution in which u = 8.0 x 10, calculate K,
for
ds.
Pbl,. The thermodynamic constant of the solubility
-9
constant of Pbl, is 7.9 x 10. Use the linear interpolation
of experimental data below.
TABLE 10-2
Activity Coefficients for Ions at 25"C
Activity Coefficient at Indicated Tonic Strength
lon
0.001
0.005
0.01
0.05
0.1
H,O
L, C,H,CO0
Na". 10,, HSO,, HCO,, H,PO,. HASO. OAC
OH F. SCN, HS, CIO,. CIO,, BrO,. 10,. Mno,
K*, CI", Br.1, CN, NO,, NO,. HCOO-
Rb", C, TI". Ag, NH,"
Mg, Be
G*. Cu, Zn, Su*, Mn, Fe*, Ni*, Co", Phchalate
St, Ba", Cd", Hg, s
Pb, Co,-, So,, CO
Hg", so,, s,0, Cr HPO,
Al*. Fe, C*, La", Ce
PO,", Fe(CN),"
Th", Z*, Ce, Sn
Fe(CN),
0.9
0.967
0.934
0.930
0.927
0.913
0.85
0.83
0.6
0.966
0.907
0.83
0.80
0.4-0.45
0.965
0.902
0.82
0.77
0.35
0.965
0.926
0.900
0.81
0.76
0.3
0.965
0.925
0,899
0.81
0.75
0.75
0.44
0.25
0.965
0.925
0,897
0,80
0.872
0.690
0.756
0.748
0.8
0.52
0.6
0.870
0.676
0.48
0.40
0,5
0.45
0.869
0.743
0.668
0.46
0.38
0.741
0.45
0.44
0.868
0.665
0.36
0.40
0.867
0.738
0.661
0.35
0.443
0.394
0.9
0.737
0.540
0.24
0.18
0.505
0.348
0.4
0.726
0.16
0.095
1.1
0.587
0.252
0.10
0.063
0.5
0.569
0.305
0.200
0.047
0.020
Source: Reprinted (adapted) with permision from J. Kielland, Am. Chem. Sor,, 1937, 59, 1675, DOI: 10.1021/ja01288a032. Copyright 1937
American Chemical Society.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 2 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY