For a certain analysis, the concentration of the analyte was determined using the model equation: Saample-Splank k CA= where CA is the analyte concentration, Searmple is the signal given by the sample, Seiank is the signal given by the blank (sample with no analyte) andk is a proportionality constant. Which of the following formulas best describes the calculation for the combined uncertainty in CA?
For a certain analysis, the concentration of the analyte was determined using the model equation: Saample-Splank k CA= where CA is the analyte concentration, Searmple is the signal given by the sample, Seiank is the signal given by the blank (sample with no analyte) andk is a proportionality constant. Which of the following formulas best describes the calculation for the combined uncertainty in CA?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:For a certain analysis, the concentration of the analyte was determined
using the model equation:
Sample - Sblank
CA=
k
where CA is the analyte concentration, Seample is the signal given by the sample, Sblank is
the signal given by the blank (sample with no analyte) and k is a proportionality constant.
Which of the following formulas best describes the calculation for the combined
uncertainty in CA?
2
usplank
+
ussample
+
(1)
Splank
CA
Ssample
CA =
(2)
4sample) + (usmlank)´+ (ux)²
CA
2
(uSsampte) +(uShlanz)
+ (+)°
(3)
CA
Ssample-Spiank
2
uk
(4)
+ (Usplane) +
Ussample
%3D
blank
CA
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