Finding and Drawing Stereogenic Centers5.45 Locate the tetrahedral stereogenic center(s) in each compound. A molecule may have one or more stereogenic centers.• stereogenic centersa.어I tetrahedral stercogenic center.b.C.d.OHOHOHOHOH OHملمهDOHe.HOHOf.OHOHOH

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Answered: Finding and Drawing Stereogenic Centers…

Chemistry

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ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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1. Can N,N-dimethyl amini make to water? If so, draw one. hydrogen your the enantiomers bonds 2 Stereochemistry 6 Draw 1-bromb - 1. ethanol in 3 dimensions Ⓒ) Draw 1-bromo -1- thanse in a Fischer projection Next to molecules in Part A and Part B draw 3. 2 males complete combustion how many grams of carbondioxide are produced? 4 when one mole of propane undergoes complete. - combustion with oxygin gas? 9 what are products? Write the balanced equation reaction and show all your work.
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8. Which of the following is the most stable staggered conformer? Me H OH Me Me OH Me OH Me H Conformer A OH HO H Conformer B OH H H Me Conformer C a. Conformer B because the anti OH groups avoid hydrogen bonding, which is a destabilizing effect. b. Conformer A because there are only two gauche interactions, and hydrogen bonding between the two OH groups is a stabilizing effect. c. Conformer C because there is no steric strain for Me-OH gauche interactions and hydrogen bonding between the two OH groups is a stabilizing effect. d. Conformer B because the large OH groups are anti to each other.
4.) Label each pair of compounds with the best choice from below: A. Enantiomers A.) a Bile=20 B.) B. Diastereomers C.) B C. Constitutional Isomers 8 11*** D.) d E.) e D. Identical Compounds Br. F) Bl me E. None *****
Draw all constitutional isomers formed by monochlorination of each attachedalkane with Cl2 and hv.
What reagents are needed to convert (CH3CH2)3CC=CH to each compound? a. (CH3CH₂)3CCOCH3 b. (CH3CH₂)3CCH₂CHO C. (CH3CH₂)3CCCl₂CH3 d. (CH3CH₂)3CC=CCH₂CH3
1. Label each of the following pairs as identical, unrelated, or conformational or constitutional isomers, enantiomers or diastereomers. Use models as needed. H CI H CI H H. H H CI CI H b. CI CI CI а. с. H, CH3 CH; H d. e. CH3 H H CH3 f. CH3 CH3 CH3 H3C CH3 H- -OH H2N- H- g. h. H3C Br H Br i. NH2 ОН CH3 CH3 H, НО СНз NH2 -H- H H2N- H- Но -CH3 `H H3C CH3 j. ОН H k. CI 1. НО Н НО Н H2N. .H CH3 H3C H3C Но н H3C OH m. n.
6. For the following molecule a. Provide the R or S stereochemistry for each chiral carbon. b. How many possible isomers can this molecule have? c. Draw 2 different diastereomers and provide their R or S stereochemistry. d. Provide the IUPAC name for the structure. HO, Br

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Finding and Drawing Stereogenic Centers 5.45 Locate the tetrahedral stereogenic center(s) in each compound. A molecule may have one or more stereogenic centers. • stereogenic centers a. 어 I tetrahedral stercogenic center. b. C. d. OH OH OH OH OH OH ملمه D OH e. HO HO f. OH OH OH