Figures 40.9 and 40.10 each have two resonances that are very small. What do the carbons causing these peaks have in common?

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Figures 40.9 and 40.10 each have two resonances that are very small. What do the carbons causing these peaks have in common?

FIG.
40.9
The ¹³C NMR spectrum of
benzoic acid (100 MHz).
FIG. 40.10
The 1³C NMR spectrum of
methyl benzoate (100 MHz).
PPM 180
PPM
T
180
0
OH
160
OCH₂
6
160
140
140
120
T
120
100
100
80
CDC1₂
T
80
CD,OD
60
60
40
40
20
T
20
0
TMS
T
0
Transcribed Image Text:FIG. 40.9 The ¹³C NMR spectrum of benzoic acid (100 MHz). FIG. 40.10 The 1³C NMR spectrum of methyl benzoate (100 MHz). PPM 180 PPM T 180 0 OH 160 OCH₂ 6 160 140 140 120 T 120 100 100 80 CDC1₂ T 80 CD,OD 60 60 40 40 20 T 20 0 TMS T 0
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