Figure 2: The conversion of ethanol to acetaldehyde How can the percentage of carbon by mass in ethanol be calculated? Choose 1 answer: A B D 2. 2 2 12.01 1 1 46.07 1 12.01 1 1 12.01 46.07 12.01 46.07 1 1 1 46.07 - 100% 100% 100% 100%
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
![### Ethanol and Its Properties
**Ethanol (CH₃CH₂OH)** is a clear, colorless liquid with a distinct odor and is the alcohol found in alcoholic beverages. Besides its use in beverages, ethanol is flammable and volatile, making it useful as a solvent, antiseptic, fuel, and in laboratory procedures. It is one of the most widely consumed recreational drugs, affecting the brain and causing symptoms like slurred speech, unsteady walk, and disturbed perception.
**Table 1: Physical properties of ethanol at 20°C**
- **Melting point:** \(-114.1^\circ C\)
- **Boiling point:** \(78.5^\circ C\)
- **Density:** \(0.79 \, \text{g/mL}\)
- **Molar mass:** \(46.07 \, \text{g/mol}^{-1}\)
### Production of Ethanol
Ethanol is produced through fermentation of sugar, catalyzed by zymase, an enzyme in yeast. This reaction results in ethanol and carbon dioxide as shown in the equation:
\[ C_6H_{12}O_6 \rightarrow 2 \, CH_3CH_2OH + 2 \, CO_2 \]
**Figure 1: The Alcohol Fermentation Reaction**
### Sources and Breakdown of Ethanol
Starches from potatoes, corn, wheat, and similar plants can be used to produce ethanol. These starches must first be converted into simple sugars by enzymes like diastase, commonly used in brewing beer.
### Metabolism of Ethanol
Once consumed, ethanol is absorbed through the stomach and small intestine, distributing throughout the body. Ethanol is toxic, and the body metabolizes it to dispose of it. In the liver, the alcohol dehydrogenase enzyme converts ethanol to acetaldehyde, which is quickly destroyed by aldehyde dehydrogenase.
\[ \text{CH}_3\text{CH}_2\text{OH} \rightarrow \text{CH}_3\text{CHO} + 2 \text{H} \]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2da5533f-8665-454a-8786-e097ba2bf066%2Ff3c0fbcb-2838-402e-afa4-c81bfc5ae6e7%2Fyfyack_processed.png&w=3840&q=75)
![**Figure 2: The conversion of ethanol to acetaldehyde**
**How can the percentage of carbon by mass in ethanol be calculated?**
*Choose 1 answer:*
- **A**
\[
2 \cdot \frac{12.01}{1} \cdot \frac{1}{46.07} \cdot 100\%
\]
- **B**
\[
2 \cdot \frac{1}{12.01} \cdot \frac{46.07}{1} \cdot 100\%
\]
- **C**
\[
2 \cdot \frac{12.01}{1} \cdot \frac{46.07}{1} \cdot 100\%
\]
- **D**
\[
2 \cdot \frac{1}{12.01} \cdot \frac{1}{46.07} \cdot 100\%
\]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2da5533f-8665-454a-8786-e097ba2bf066%2Ff3c0fbcb-2838-402e-afa4-c81bfc5ae6e7%2Ffcj6fkq_processed.png&w=3840&q=75)

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