f. Consider the following coupled redox reaction. O2 + 2NADH + 2H* = 2H₂O + 2NAD+ Calculate AG" (at 310 K) if the standard reduction potentials for O2 and NAD+ are 0.815V and -0.315V respectively. g. If you wanted to shift the above reaction in f. to the left, how would you adjust the pH? Explain briefly.
f. Consider the following coupled redox reaction. O2 + 2NADH + 2H* = 2H₂O + 2NAD+ Calculate AG" (at 310 K) if the standard reduction potentials for O2 and NAD+ are 0.815V and -0.315V respectively. g. If you wanted to shift the above reaction in f. to the left, how would you adjust the pH? Explain briefly.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![6.
f. Consider the following coupled redox reaction.
O₂ + 2NADH + 2H* = 2H₂O + 2NAD+
Calculate AG" (at 310 K) if the standard reduction potentials for O2 and
NAD+ are 0.815V and -0.315V respectively.
g. If you wanted to shift the above reaction in f. to the left, how would you
adjust the pH? Explain briefly.
Lab-related questions.
a. In lab, you made a 5 M NaCl stock solution. How would you make a 10-
mL 0.5 M NaCl solution from your stock solution?
i.
9 mL 5 M NaCl and 1 mL water
ii.
5 mL 5 M NaCl and 5 mL water
iii.
1 mL 5 M NaCl and 9 mL water
iv.
0.1 mL 5 M NaCl and 9.9 mL water
b. In the first week of lab, you made a pH 7.4 phosphate buffer by mixing
some H₂PO4 with HPO4². The pK₂ of H₂PO4 is 7.2. Which of the following
is true?
i.
ii.
iii.
iv.
7
More H₂PO4* needs to be added because the pH > pKa
More HPO4²- needs to be added because the pH > pKa
More H₂PO4 needs to be added because more acid is needed to
maintain a pH of 7.4.
More HPO4²- needs to be added because it is more stable.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F33597ee9-2b67-48b1-99d7-550b18872d77%2Fdd2f2f90-6ac6-45f6-9662-6c184e3e9b04%2Frpliq1h_processed.png&w=3840&q=75)
Transcribed Image Text:6.
f. Consider the following coupled redox reaction.
O₂ + 2NADH + 2H* = 2H₂O + 2NAD+
Calculate AG" (at 310 K) if the standard reduction potentials for O2 and
NAD+ are 0.815V and -0.315V respectively.
g. If you wanted to shift the above reaction in f. to the left, how would you
adjust the pH? Explain briefly.
Lab-related questions.
a. In lab, you made a 5 M NaCl stock solution. How would you make a 10-
mL 0.5 M NaCl solution from your stock solution?
i.
9 mL 5 M NaCl and 1 mL water
ii.
5 mL 5 M NaCl and 5 mL water
iii.
1 mL 5 M NaCl and 9 mL water
iv.
0.1 mL 5 M NaCl and 9.9 mL water
b. In the first week of lab, you made a pH 7.4 phosphate buffer by mixing
some H₂PO4 with HPO4². The pK₂ of H₂PO4 is 7.2. Which of the following
is true?
i.
ii.
iii.
iv.
7
More H₂PO4* needs to be added because the pH > pKa
More HPO4²- needs to be added because the pH > pKa
More H₂PO4 needs to be added because more acid is needed to
maintain a pH of 7.4.
More HPO4²- needs to be added because it is more stable.
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