f. Consider the following coupled redox reaction. O2 + 2NADH + 2H* = 2H₂O + 2NAD+ Calculate AG" (at 310 K) if the standard reduction potentials for O2 and NAD+ are 0.815V and -0.315V respectively. g. If you wanted to shift the above reaction in f. to the left, how would you adjust the pH? Explain briefly.

Chemistry: Principles and Reactions
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Chapter17: Electrochemistry
Section: Chapter Questions
Problem 100QAP: Consider the following standard reduction potentials:...
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6.
f. Consider the following coupled redox reaction.
O₂ + 2NADH + 2H* = 2H₂O + 2NAD+
Calculate AG" (at 310 K) if the standard reduction potentials for O2 and
NAD+ are 0.815V and -0.315V respectively.
g. If you wanted to shift the above reaction in f. to the left, how would you
adjust the pH? Explain briefly.
Lab-related questions.
a. In lab, you made a 5 M NaCl stock solution. How would you make a 10-
mL 0.5 M NaCl solution from your stock solution?
i.
9 mL 5 M NaCl and 1 mL water
ii.
5 mL 5 M NaCl and 5 mL water
iii.
1 mL 5 M NaCl and 9 mL water
iv.
0.1 mL 5 M NaCl and 9.9 mL water
b. In the first week of lab, you made a pH 7.4 phosphate buffer by mixing
some H₂PO4 with HPO4². The pK₂ of H₂PO4 is 7.2. Which of the following
is true?
i.
ii.
iii.
iv.
7
More H₂PO4* needs to be added because the pH > pKa
More HPO4²- needs to be added because the pH > pKa
More H₂PO4 needs to be added because more acid is needed to
maintain a pH of 7.4.
More HPO4²- needs to be added because it is more stable.
Transcribed Image Text:6. f. Consider the following coupled redox reaction. O₂ + 2NADH + 2H* = 2H₂O + 2NAD+ Calculate AG" (at 310 K) if the standard reduction potentials for O2 and NAD+ are 0.815V and -0.315V respectively. g. If you wanted to shift the above reaction in f. to the left, how would you adjust the pH? Explain briefly. Lab-related questions. a. In lab, you made a 5 M NaCl stock solution. How would you make a 10- mL 0.5 M NaCl solution from your stock solution? i. 9 mL 5 M NaCl and 1 mL water ii. 5 mL 5 M NaCl and 5 mL water iii. 1 mL 5 M NaCl and 9 mL water iv. 0.1 mL 5 M NaCl and 9.9 mL water b. In the first week of lab, you made a pH 7.4 phosphate buffer by mixing some H₂PO4 with HPO4². The pK₂ of H₂PO4 is 7.2. Which of the following is true? i. ii. iii. iv. 7 More H₂PO4* needs to be added because the pH > pKa More HPO4²- needs to be added because the pH > pKa More H₂PO4 needs to be added because more acid is needed to maintain a pH of 7.4. More HPO4²- needs to be added because it is more stable.
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